“…After calcining at 800 • C for 1 h, the peaks at 1080, 850 and 733 cm −1 disappear, and the sharp peak at 565 cm −1 associated with the vibration of Y-O is observed, indicating the formation of Y 2 O 3 [23]. Moreover, as the particle size decreases to nanometer range, due to the high surface-to-volume ratio, large amount of H 2 O and CO 2 in atmosphere is absorbed on the surface of particles to form CO 3 2− and OH − . Thus the bands around 3390, 1520 and 1400 cm −1 in calcined powder gradually strengthen along with the decrease of particle size.…”