“…The emission-tunable approaches used for achieving the solid solutions have been widely described in the archival literatures, but strategies are usually focused on isostructural crystals that incorporate dopants like Eu 2+ [6], Ce 3+ [7], Mn 2+ [8], and Bi 3+ [9] ions whose spectral characteristics are very sensitive to the nature of their nearby chemical microenvironment, owing to the outer character of the emitting states. As a matter of comparison, the well-shielded 4f ions (e.g., Eu 3+ [10], Pr 3+ [11], Tb 3+ [12], Tm 3+ [13], Er 3+ [14][15] etc) and other 3d ions like Mn 4+ [16], and Cr 3+ [17]) usually exhibit their fixed spectral shape and positions, making the tunable-emission being less to realize in single ion doped solid solutions.…”
Manipulating the secondary cation ratio in the ScVxP1−xO4:Bi3+ solid solution allows tuning of the excitation tail from 340 to 425 nm and the corresponding emission maximum from 455 to 641 nm, without significant reabsorption.
“…The emission-tunable approaches used for achieving the solid solutions have been widely described in the archival literatures, but strategies are usually focused on isostructural crystals that incorporate dopants like Eu 2+ [6], Ce 3+ [7], Mn 2+ [8], and Bi 3+ [9] ions whose spectral characteristics are very sensitive to the nature of their nearby chemical microenvironment, owing to the outer character of the emitting states. As a matter of comparison, the well-shielded 4f ions (e.g., Eu 3+ [10], Pr 3+ [11], Tb 3+ [12], Tm 3+ [13], Er 3+ [14][15] etc) and other 3d ions like Mn 4+ [16], and Cr 3+ [17]) usually exhibit their fixed spectral shape and positions, making the tunable-emission being less to realize in single ion doped solid solutions.…”
Manipulating the secondary cation ratio in the ScVxP1−xO4:Bi3+ solid solution allows tuning of the excitation tail from 340 to 425 nm and the corresponding emission maximum from 455 to 641 nm, without significant reabsorption.
“…28 Meanwhile, there are a lot of evidence about the iso-structural of orthorhombic Na 3 Nd(PO 4 ) 2 with other sodium and rare-earth double orthophosphates Na 3 -RE(PO 4 ) 2 (RE ¼ Y, La-Er). 10,12,29,30 Here the crystal structure data of Na 3 Nd(PO 4 ) 2 is used as a starting model to rene the crystal structure. Fig.…”
Section: Phase Identication and Crystal Structurementioning
A series of Tb3+and/or Eu3+doped Na3La(PO4)2phosphors were successfully synthesized and their crystal structure and photoluminescence (PL) properties were investigated in detail.
“…When excited at 293 nm, the AP/SMA polymer exhibited a broad emission band at 300–550 nm (maximum wavelength = 381 nm). As shown in Figure (b), several sharp lines in the range 300–500 nm were ascribed to the intraconfigurational 4f–4f transitions of the Eu(III) ions: 7 F 0 → 5 F 4 (303 nm), 5 H 6 (318 nm), 5 D 4 (362 nm), 5 G J (376 nm), 5 L 7 (383 nm), 5 L 6 (395 nm), and 5 D 3 (417 nm), respectively . We found that the excitation intensity at 395 nm was the highest in the excitation spectrum; this is very attractive for applications such as the red component of tricolor luminescence materials .…”
Copolymers of aniline-g-poly(styrene-co-maleic anhydride) (AP/SMA) and its lanthanide(III) (Ln) ion complexes [Ln-AP/ SMA (where Ln 5 La, Eu, Tb, or Yb)] were synthesized and characterized by elemental analysis, Fourier transform infrared spectroscopy, 1 H-NMR analysis, thermogravimetry-differential thermal analysis, and differential scanning calorimetry. At room temperature, the fluorescence spectra showed that the AP/SMA polymer had a strong, broad emission band at 300-550 nm (maximum wavelength 5 381 nm) under excitation at 293 nm. Moreover, the respective characteristic emissions of Eu(III) and Tb(III) ions were observed in their Ln(III) complexes. Both the Eu(III) complexes and Tb(III) complexes showed excellent solvent resistance, good thermal stability, high quantum yield, and a long fluorescent lifetime. Therefore, the AP/SMA polymer and the fluorescent Ln-AP/SMA complexes have a promising future in applications of fluorescence materials. In addition, the reaction spontaneously reached equilibrium only after 5 min in the water phase; this showed that AP/SMA has good application prospects in the adsorption of Ln ions.
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