Luminescent monomeric and polymeric cuprous halide complexes with 1,2-bis(3,5-dimethylpyrazol-1-ylmethyl)-benzene as ligand

Hypso- or bathochromic phosphorescent mechanochromic mononuclear Cu(i) complexes with a bis(2-diphenylphosphinophenyl)ether auxiliary ligand

“…[32][33][34][35][36][37][38][39][40][41][42][43][44] In recent years, the exploitation of structurally novel Cu(I) complexes has received much attention owing to their low cost and superior photophysical properties of Cu(I)-containing molecules. [45][46][47][48][49][50][51][52][53] Although stimuli-responsive Cu(I) complexes had been explored in the 1970s, the number of mechanoluminochromic Cu(I) complexes is still inadequate. 54 Noticeably, Perruchas et al developed a reversible mechanochromic tetranuclear Cu (I) iodide cluster in 2010, and its pale green solid PL was changed into yellow solid PL upon grinding.…”