Luminescent Hydride-Free [Cu7(SC5H9)7(PPh3)3] Nanocluster: Facilitating Highly Selective C–C Bond Formation
Sourav Biswas,
Amit Pal,
Milan Kumar Jena
et al.
Abstract:Amidst burgeoning interest, atomically precise copper nanoclusters (Cu NCs) have emerged as a remarkable class of nanomaterials distinguished by their unparalleled reactivity. Nonetheless, the synthesis of hydride-free Cu NCs and their role as stable catalysts remain infrequently explored. Here, we introduce a facile synthetic approach to fabricate a hydride-free [Cu 7 (SC 5 H 9 ) 7 (PPh 3 ) 3 ] (Cu 7 ) NC and delineate its photophysical properties intertwined with their structural configuration. Moreover, the… Show more
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