Luminescent cadmium(II) complexes with benzyl and chlorobenzyl benzimidazole derivatives and closo-decaborate anion

Korolenko, Svetlana E.; Кубасов, А. С.; Son, Ahjeong; Голубев, А. В.; Козерожец, И. В.; Бурлов, А. С.; Диваева, Л. Н.; Авдеева, В. В.; Малинина, Е. А.; Кузнецов, Н. Т.

doi:10.1016/j.ica.2023.121654

Cited by 6 publications

(1 citation statement)

References 53 publications

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“…Based on the obtained complexes with coordinated solvent molecules, we can expand the methodology for the preparation of compounds of the desired composition. It is known that these complex compounds containing easily leaving groups, in particular, solvent molecules, are promising agents for the targeted preparation of compounds of the required composition by the mechanochemical activation, thermolysis, , complexation in solution, − catalysis, ,, and as membrane carriers for the transport of hydrophilic cargos …”

Section: Introductionmentioning

confidence: 99%

Effect of the Presence of Oxysolvents on Compositions and Structures of Silver(I) Complexes with Boron Cluster Anion [B₁₂Cl₁₂]^2–

Golubev,

Kubasov,

Malinina

et al. 2024

Crystal Growth & Design

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For the first time, a systematic study of the behavior of Ag 2 [B 12 Cl 12 ] in oxygencontaining organic solvents of various nature (acetone, N,N-dimethylformamide (DMF), dimethoxyethane (DME), methanol (CH 3 OH), and tetrahydrofuran (THF)) was conducted. The solvents used were found to compete with the perchlorinated [B 12 Cl 12 ] 2− anion, forming a silver(I) coordination polyhedron. A number of silver(I) coordination compounds of various compositions and structures with solvent molecules acting as ligands were obtained and characterized by physicochemical methods. The structures of polymer complexes {Ag 2 (solv) x [B 12 Cl 12 ]} n (x = 4, solv = acetone (1), DMF (2), CH 3 OH (4), THF (7); x = 2, solv = DME (3)) with the coordinated [B 12 Cl 12 ] 2− anion, as well as coordination compounds [Ag(THF) 3 ] 2 [B 12 Cl 12 ] (5) and [Ag(THF) 4 Ag(THF) 2 ][B 12 Cl 12 ] (6) with the boron cluster anion as a counterion were determined by single-crystal X-ray diffraction. Furthermore, the complexation of Ag 2 [B 12 Cl 12 ] with the organic ligands 18-crown-6 (L 1 ) and 4-methylmorpholine (L 2 ) was investigated. Salts with the complex cations [Ag L 1 (CH 3 OH)] + (8) and [Ag(L 2 ) 2 ] + (9) were isolated. Based on the results obtained, a plausible pathway for the process of complexation of Ag 2 [B 12 Cl 12 ] with organic ligand L in oxygen-containing organic solvents was proposed. The data were confirmed using 109 Ag NMR spectroscopy of solutions of Ag 2 [B 12 Cl 12 ] salt in individual solvents and their mixtures.

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Section: Introductionmentioning

confidence: 99%

Effect of the Presence of Oxysolvents on Compositions and Structures of Silver(I) Complexes with Boron Cluster Anion [B₁₂Cl₁₂]^2–

Golubev,

Kubasov,

Malinina

et al. 2024

Crystal Growth & Design

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Cd(II) and Zn(II) complexes with 2-mercaptopyridine: Synthesis, crystal structure, Hirshfeld surface analysis, luminescent properties, aggregation behaviours, current-voltage characteristic and antibacterial assay

Das,

Arshad Hussain,

Banik

et al. 2024

Polyhedron

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Structural variety of benzimidazole coordinated zinc(II) and cadmium(II) complexes with closo-decaborate anion

Nikiforova,

Kubasov,

Goeva

et al. 2024

Polyhedron

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Luminescent cadmium(II) complexes with benzyl and chlorobenzyl benzimidazole derivatives and closo-decaborate anion

Cited by 6 publications

References 53 publications

Effect of the Presence of Oxysolvents on Compositions and Structures of Silver(I) Complexes with Boron Cluster Anion [B₁₂Cl₁₂]^2–

Effect of the Presence of Oxysolvents on Compositions and Structures of Silver(I) Complexes with Boron Cluster Anion [B₁₂Cl₁₂]^2–

Cd(II) and Zn(II) complexes with 2-mercaptopyridine: Synthesis, crystal structure, Hirshfeld surface analysis, luminescent properties, aggregation behaviours, current-voltage characteristic and antibacterial assay

Structural variety of benzimidazole coordinated zinc(II) and cadmium(II) complexes with closo-decaborate anion

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Luminescent cadmium(II) complexes with benzyl and chlorobenzyl benzimidazole derivatives and closo-decaborate anion

Cited by 6 publications

References 53 publications

Effect of the Presence of Oxysolvents on Compositions and Structures of Silver(I) Complexes with Boron Cluster Anion [B12Cl12]2–

Effect of the Presence of Oxysolvents on Compositions and Structures of Silver(I) Complexes with Boron Cluster Anion [B12Cl12]2–

Cd(II) and Zn(II) complexes with 2-mercaptopyridine: Synthesis, crystal structure, Hirshfeld surface analysis, luminescent properties, aggregation behaviours, current-voltage characteristic and antibacterial assay

Structural variety of benzimidazole coordinated zinc(II) and cadmium(II) complexes with closo-decaborate anion

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Product

Resources

About

Effect of the Presence of Oxysolvents on Compositions and Structures of Silver(I) Complexes with Boron Cluster Anion [B₁₂Cl₁₂]^2–

Effect of the Presence of Oxysolvents on Compositions and Structures of Silver(I) Complexes with Boron Cluster Anion [B₁₂Cl₁₂]^2–