Abstract:Bis-amidinate indium(III) monochlorides InCl (5), and [( t BuN) 2 C(1-pyrene)] 2 InCl (6) were prepared by the reaction of the corresponding Li-amidinate ligand with InCl 3 . Single crystal X-ray analysis of compounds 1, 2, 4, and 5 reveals that the In(III) center is bound with two chelating amidinate ligands. The overall coordination geometry around In(III) is distorted trigonal bipyramidal with the chloride occupying one of the equatorial positions. The photophysical properties of these compounds have been a… Show more
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