“…Contrary to Adnan Khan's research, Er 3+ not only cause the quenching of Tm 3+ [30], but also receives energy from Tm 3+ (Er: 4 I 13/2 + Tm: 3 H 5 → Er: 4 F 9/2 + Tm: 3 H 6 ), explaining the small increase in green and red emissions. When the Er 3+ doping concentration was 0.6 mol%, three emissions exhibited a strong peak, possibly because of the increase in luminescent centers, weakening of lattice symmetry, and release of dormant RE ions located in the symmetric positions of the Y 2 O 3 lattice [31,32]. Increasing the Er 3+ concentration up to 1.4 mol% resulted in emission enhancement, and the enhancement of the green and red emissions should be attributed to the energy from Tm 3+ .…”
In this study, a series of well-crystallized Yb3+/Er3+/Tm3+-tridoped Y2O3-ZnO ceramic nano-phosphors were prepared using sol–gel synthesis, and the phosphor structures were studied using X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis. The phosphors were well crystallized and exhibited a sharp-edged angular crystal structure and mesoporous structure consisting of 270 nm nano-particles. All phosphors generated blue, green, and red emission bands attributed to Tm: 1G4→3H6, Er: 2H11/2 (4S3/2)→4I15/2, and Er: 4F9/2→4I15/2 radiative transitions, respectively. Increasing in luminescent centers, weakening of lattice symmetry, and releasing of dormant rare earth ions can enhance all emissions. Er3+ can obtain energy from Tm3+ to enhance green and red emission. These colors can be tuned by optimizing the doping concentrations of the Er3+ ion. The color coordinates were adjusted by tuning both the Er3+ concentration and excitation laser pump power to shift the color coordinates and correlated color temperature. The findings of this study will broaden the potential practical applications of phosphors.
“…Contrary to Adnan Khan's research, Er 3+ not only cause the quenching of Tm 3+ [30], but also receives energy from Tm 3+ (Er: 4 I 13/2 + Tm: 3 H 5 → Er: 4 F 9/2 + Tm: 3 H 6 ), explaining the small increase in green and red emissions. When the Er 3+ doping concentration was 0.6 mol%, three emissions exhibited a strong peak, possibly because of the increase in luminescent centers, weakening of lattice symmetry, and release of dormant RE ions located in the symmetric positions of the Y 2 O 3 lattice [31,32]. Increasing the Er 3+ concentration up to 1.4 mol% resulted in emission enhancement, and the enhancement of the green and red emissions should be attributed to the energy from Tm 3+ .…”
In this study, a series of well-crystallized Yb3+/Er3+/Tm3+-tridoped Y2O3-ZnO ceramic nano-phosphors were prepared using sol–gel synthesis, and the phosphor structures were studied using X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis. The phosphors were well crystallized and exhibited a sharp-edged angular crystal structure and mesoporous structure consisting of 270 nm nano-particles. All phosphors generated blue, green, and red emission bands attributed to Tm: 1G4→3H6, Er: 2H11/2 (4S3/2)→4I15/2, and Er: 4F9/2→4I15/2 radiative transitions, respectively. Increasing in luminescent centers, weakening of lattice symmetry, and releasing of dormant rare earth ions can enhance all emissions. Er3+ can obtain energy from Tm3+ to enhance green and red emission. These colors can be tuned by optimizing the doping concentrations of the Er3+ ion. The color coordinates were adjusted by tuning both the Er3+ concentration and excitation laser pump power to shift the color coordinates and correlated color temperature. The findings of this study will broaden the potential practical applications of phosphors.
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