Luminescence properties of Sn-containing microcrystals in CsBr:Sn crystal

Abstract

Formation of CsSnBr 3 microcrystals in CsBr:Sn (1 mol.%) crystals is revealed after the long-term annealing (t = 100 h, T = 200 0 С). Luminescent-kinetic parameters of CsBr:Sn (1 mol.%) crystals are measured using the excitation with synchrotron radiation. The process of energy transfer from the host to the aggregates is discussed.

Bromine Precursor Mediated Synthesis of Shape Controlled Cesium Bromide Nanoplatelets and Their Mechanism Study by DFT Calculation

“…CsX is an ionic compound with two interlocking Pm 3̅ m primitive cubic cells, where one cube is Cs + and the other is X – . Cations such as Pb 2+ , Sn 2+ , and Eu 2+ can be included in the structure to form a doped CsX structure, which has various optical properties. − Cesium halide (CsX) can be used as a detector and has good electron-emitting properties in the ultraviolet (UV) region . Recently, we reported a green-emitting perovskite, CsPbBr 3 , in the bulk CsBr matrix, which was fabricated by adding a Pb precursor to a CsBr solid .…”

Dispersion Law with a Low-Energy Non-Parabolicity for the Charge Carriers in the In4Se3Crystal and Related Effects

“…Due to the presence of the symmetry center in this crystal, taking into account the spin and spin-orbit interaction cannot change the functional dependence of this dispersion law. It was used for an explanation of some peculiarities of the kinetic properties in this crystal [7]. The existence of the condenson states owing to the electron-phonon interaction [3,5] is also related to this dispersion law.…”