Abstract. In this work we have grown single crystals K x (NH 4 ) 2-x SO 4 (x 1.75), which belong to a potassium-ammonium sulfate family, and studied their roomtemperature structure. Spectral dependences of the principal refractive indices and principal optical birefringences are measured in the visible region. Anomalous birefringence dispersion is observed along the light propagation direction parallel to the principal x axis. According to our birefringence extrapolation based on the Sellmeier fit for the refractive indices, the symmetry of optical indicatrix at the room temperature should increase at the light wavelength λ IP 1350±60 nm. This corresponds to a specific 'isotropic point' defined by the condition n x (λ IP ) = n y (λ IP ), which has not been detected in either K 2 SO 4 or (NH 4 ) 2 SO 4 crystals.