The paper updates and summarizes contemporary applications of capillary optical fibers. Some of these applications are straight consequence of the classical capillary properties and capillary devices like: rheometry, electrophoresis, column chromatography (gas and liquid). Some new applications are tightly connected with co-propagation (or counterpropagation) of micro-mass together with optical wave -evanescent or of considerable intensity. In the first case, the optical wave is propagated in a narrow (more and more frequently single-mode) optical ring core adjacent to the capillary hole. The optical propagation is purely refractive. In the second case, the intensity maximum of optical wave is on the capillary long axis, i.e. in the center of the hole. The optical propagation is purely photonic, i.e. in a Bragg waveguide (one dimensional photonic band-gap). The capillary hole is filled with vacuum or with propagated matter (gas, liquid, single atoms, continuous particle arrangement). Optical capillaries, filamentary and embedded, are turning to a fundamental component of nano-and micro MOEMS.
CLASSICAL CAPILLARY TECHNIQUESA capillary is an arbitrary pipe of small internal diameter. In analytical chemistry and spectroscopy, the capillary is high quality, highly flexible, ultra-pure silica glass pipe of internal dimensions in the range 1-2000µm (typically 2-700µm) covered continuously by polyamide (or other polymer) or metal layer. External diameters of capillaries are in the range 90-3500µm (typically 90-850µm). Capillaries are made of natural fused quartz, synthetic silica or doped silica (by fluorine), borosilicate glasses and only exceptionally (for research purposes) from high silica soft glasses.The world market for technical capillaries is of the order of several hundreds of MЄ [18]. They are sold in spools, cut out pieces with connectors. The advantages of pure silica capillaries in technical applications are the following: they have excellent mechanical strength, are very flexible, while jacketed are very resistant to abrasion and scratching, have very smooth internal and external surface, internal surface is chemically passive and very clean, capillary may be pulled to precisely defined dimensions -internal and external, dimensions are stable and repeatable in function of length, internal surface may be modified, are resistant to breakage (continuity of internal channel), are transparent from deep UV to IR (after local removing of the polymer jacket -opening a transmission window), are extremely resistant to wide range of temperature changes, are resistant to electrical short circuits, can easily be cut and cleaved, are easily covered with big adhesion strength by a number of jacketing materials.The idea of capillary applications is strictly connected with the very beginnings of optical fiber technology. In the early seventies the capillaries were filled with ultra-pure tetra. Low loss optical fibers of liquid core were formed in this way. Such fibers were manufactured in many laboratories all over the wo...