Abstract:Within the framework of the linked ordering schemes theory of vibration-rotational interactions in molecules the introduction of Herman-Wallis factors into intensities of multiquantum vibrational transitions has been presented in effective dipole moment operator by sequences of types Meff M1 +M2 + M3 + ..., where n = 1, 2, 3The results of grouptheoretical analysis of tensorial parameters in M1 (n 1 ÷ 3) for symmetric top molecules have been presented.Generalization of these results for multiquantum vibrational… Show more
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