Abstract:Purpose:
Here, we present the successful preparation of a highly efficient gallic acid resin grafted with magnetic nanoparticles (MNPs) and containing a branched brush polymeric shell.
Methods:
Using a convenient co-precipitation method, we prepared Fe
3
O
4
nanoparticles stabilized by citric acid. These nanoparticles underwent further silica modification and amino functionalization followed by gallic acid functionalization on the… Show more
“…A continuous increased was observed until 45 °C; afterwards the conversion decreased ( Figure 2). The obtained results are in concordance with the literature data, reporting an increased termostability of CaL-B bioconjugates as compared with the free enzyme [59]. As consequence 45 °C was chosen as optimal temperature, all further experiments were performed at this temperature.…”
Lipase B from Candida antarctica immobilized by covalent binding on sebacoyl-activated chitosan-coated magnetic nanoparticles proved to be an efficient biocatalyst (49.2–50% conversion in 3–16 h and >96% enantiomeric excess) for the enzymatic kinetic resolution of some racemic heteroarylethanols through transesterification with vinyl acetate. Under optimal conditions (vinyl acetate, n-hexane, 45 °C), the biocatalyst remains active after 10 cycles.
“…A continuous increased was observed until 45 °C; afterwards the conversion decreased ( Figure 2). The obtained results are in concordance with the literature data, reporting an increased termostability of CaL-B bioconjugates as compared with the free enzyme [59]. As consequence 45 °C was chosen as optimal temperature, all further experiments were performed at this temperature.…”
Lipase B from Candida antarctica immobilized by covalent binding on sebacoyl-activated chitosan-coated magnetic nanoparticles proved to be an efficient biocatalyst (49.2–50% conversion in 3–16 h and >96% enantiomeric excess) for the enzymatic kinetic resolution of some racemic heteroarylethanols through transesterification with vinyl acetate. Under optimal conditions (vinyl acetate, n-hexane, 45 °C), the biocatalyst remains active after 10 cycles.
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