“…At present, a variety of RE-doped materials have been extensively studied to extract the characteristic emissions of RE ions. ,− However, their emission is often significantly quenched at high RE density due to the inevitable ion precipitation induced by the degraded lattice matrix of their host material and the increased cross-relaxation between neighboring RE ions as a result of the reduced ion spacing. − , The limited stable RE density in most RE-doped materials has become a major challenge in supporting high optical gain for monolithically integrated photonics and optoelectronics (e.g., optical amplifiers and lasers). − As a class of potential materials to address this challenge, monocrystalline RE silicates have attracted particular research interest due to their high RE density without ion precipitation and emission quenching. Furthermore, RE silicates exhibit additional advantages, including a highly symmetric crystal field, excellent chemical/thermal stability, and a low Schottky barrier on n -type silicon. − In addition, considering that RE silicates are lattice-matched with monocrystalline silicon and silicon is chemically involved in the formation of RE silicates, the combination of RE silicates and silicon nanostructures would provide exciting opportunities for monolithic integration of photonics with silicon, which has been the subject of active research. − Therefore, RE silicate crystals have been proposed for the implementation of modern solid-state phosphors and monolithic lasers. ,,, While RE silicates have been extensively studied for a long time, their low-dimensional nanostructures were less explored. In 2005, Choi et al reported the growth of Si/Silica/Er 2 Si 2 O 7 core–shell nanowire heterostructures with carrier-mediated 1.53 μm Er 3+ luminescence consisting of a series of very sharp peaks .…”