Low‐Temperature Synthesis and Thermodynamic and Electrical Properties of Barium Titanate Nanorods

Abstract

Studies regarding the morphology dependence of the perovskite-type oxides functional materials properties are of recent interest. With this aim, nanorods (NRs) and nanocubes (NCs) of barium titanate (BaTiO 3 ) have been successfully synthesized via a hydrothermal route at temperature as low as 408 K, employing barium acetate, titanium isopropoxide, and sodium hydroxide as reagents without any surfactant or template. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray powder diffraction (XRD), used for the morphology and structure analyses, showed that the NRs were formed by an oriented attachment of the NCs building-blocks with 20 nm average crystallites size. The thermodynamic properties represented by the relative partial molar free energies, enthalpies, and entropies of the oxygen dissolution in the perovskite phase, as well as the equilibrium partial pressure of oxygen, indicated that NRs powders have lower oxygen vacancies concentration than the NCs. This NRs characteristic, together with higher tetragonallity of the structure, leads to the enhancement of the dielectric properties of BaTiO 3 ceramics. The results presented in this work show indubitably the importance of the nanopowders morphology on the material properties.

Introductory Chapter: Structure-Processing-Properties Relationships in Stoichiometric and Nonstoichiometric Oxides

“…This means that a great deal of attention must be turned to the energetic parameters which play an important role in the overall properties and behavior of materials. Exploring the relationships between morphology and thermodynamic properties of nanocrystalline BaTiO 3 , it was shown that the enhancement of the dielectric properties for the BaTiO 3 hydrothermal-prepared powders with 1D morphology, comparatively with nanocubes or hollow-type morphologies, is strongly correlated with the increase in the binding energy of oxygen in the perovskite structure [62,63].…”

Synthesis and growth studies of barium titanates: 0−D and 1−D nanostructures using hydrogen titanate precursor

“…have been synthesized by various routes. The most commonly applied methods include hydrothermal, molten-salt synthesis and electrospinning approach [5][6][7][8][9][10][11][12]. Among the various approaches, hydrothermal process is the most widely used technique due to its low cost, scalable, easy synthesis and environmental friendly.…”