“…In Table 1, the experimental energy levels of the V 3+ ion doped in Al 2 O 3 crystal are listed [10][11][12]. These energies are measured in s and p polarization.…”
Section: Experimental and Theoretical Datamentioning
confidence: 99%
“…The optical spectra and the experimental energy data of V 3+ :Al 2 O 3 [10][11][12] and of Ni 2+ :LiNbO 3 [20,37] are used for our theoretical analysis. The LS-ground term of the 3d 2 and 3d 8 configurations is 3 F, which is split by octahedral CF into 3 T 1g , 3 T 2g and 3 A 2g states.…”
Section: Experimental and Theoretical Datamentioning
confidence: 99%
“…The Ni 2+ ions are surrounded by six oxygen atoms with a slight tetragonal distortion from octahedral symmetry. Previous studies of V 3+ :Al 2 O 3 [5][6][7][8][9][10][11][12] and of Ni 2+ :LiNbO 3 [18][19][20][21][22][23][24] were based on the approximated C 3v or O h rather than that of the actual C 3 symmetry. Such approximations may not provide a reliable insight into the energy-level structure for V 3+ electronic structure of 3d N ions at arbitrary symmetry sites in crystals, including 3d 2 and 3d 8 ions at trigonal C 3 symmetry sites, an extended crystal-field (CF) analysis computer package has been developed [25,26].…”
Section: Introductionmentioning
confidence: 99%
“…One way to achieve tunable laser oscillation is by using transition metal and rareearth ions as laser active ions in crystals [1][2][3][4]. Since V 3+ :Al 2 O 3 crystal is technologically a important material, a great deal of theoretical and experimental studies have been carried out [5][6][7][8][9][10][11][12][13]. The vanadium ion V 3+ (3d 2 ) readily substitutes for an aluminium ion A1 3+ in A1 2 O 3 [13].…”
“…In Table 1, the experimental energy levels of the V 3+ ion doped in Al 2 O 3 crystal are listed [10][11][12]. These energies are measured in s and p polarization.…”
Section: Experimental and Theoretical Datamentioning
confidence: 99%
“…The optical spectra and the experimental energy data of V 3+ :Al 2 O 3 [10][11][12] and of Ni 2+ :LiNbO 3 [20,37] are used for our theoretical analysis. The LS-ground term of the 3d 2 and 3d 8 configurations is 3 F, which is split by octahedral CF into 3 T 1g , 3 T 2g and 3 A 2g states.…”
Section: Experimental and Theoretical Datamentioning
confidence: 99%
“…The Ni 2+ ions are surrounded by six oxygen atoms with a slight tetragonal distortion from octahedral symmetry. Previous studies of V 3+ :Al 2 O 3 [5][6][7][8][9][10][11][12] and of Ni 2+ :LiNbO 3 [18][19][20][21][22][23][24] were based on the approximated C 3v or O h rather than that of the actual C 3 symmetry. Such approximations may not provide a reliable insight into the energy-level structure for V 3+ electronic structure of 3d N ions at arbitrary symmetry sites in crystals, including 3d 2 and 3d 8 ions at trigonal C 3 symmetry sites, an extended crystal-field (CF) analysis computer package has been developed [25,26].…”
Section: Introductionmentioning
confidence: 99%
“…One way to achieve tunable laser oscillation is by using transition metal and rareearth ions as laser active ions in crystals [1][2][3][4]. Since V 3+ :Al 2 O 3 crystal is technologically a important material, a great deal of theoretical and experimental studies have been carried out [5][6][7][8][9][10][11][12][13]. The vanadium ion V 3+ (3d 2 ) readily substitutes for an aluminium ion A1 3+ in A1 2 O 3 [13].…”
The theoretical expressions for the magnetic susceptibility and g-values of trigonally distorted octahedral V3+ ion have been developed on the basis of molecular orbital method of Stevens
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.