The low-temperature properties of a family of ytterbium-based compounds with the composition Yb 2 T 3 X 9 (TϭRh, Ir; XϭAl, Ga) are studied by means of magnetic susceptibility, electrical resistivity, thermoelectric power, and specific-heat C P measurements. Yb 2 Rh 3 Al 9 and Yb 2 Ir 3 Al 9 show the typical properties of heavyfermion antiferromagnets, namely they order at T N ϭ3.5 K and T N ϭ5.5 K, respectively, their C P /T data extrapolate to ␥ o ϭ230 mJ/mol Yb K 2 below 0.5 K, and their entropy gain at T N reaches 0.6R ln 2 only. The transport data show evidence of low-lying crystal-electric-field levels separated by ⌬ CEF Ӎ30 K from the ground-state doublet. On the contrary, Yb 2 Rh 3 Ga 9 and Yb 2 Ir 3 Ga 9 show mixed-valent behavior, as observed in most Yb-based intermetallics. The effect of the ligands on the ground-state properties is discussed and compared with other lanthanide-and actinide-based isostructural R 2 T 3 X 9 homologues.