“…14,15 Due to the scarcity and high cost to obtain indium metal, new 3 systems, like Sn-doped In 2 O 3 (ITO) and corundum-type In 2-2x Zn x Sn x O 3 (x ≤ 0.4, or ZITO), have been developed to cut the prize of the production system. [16][17][18] At ambient conditions In 2 O 3 usually crystallizes in the cubic bixbyite-type phase (space group (SG) Ia-3, N. 206, Z=16), 19 and other phases of In 2 O 3 can be obtained by the application of pressure and temperature: rhombohedral corundum-type (SG R-3c, N. 167, Z=6), orthorhombic Rh 2 O 3 -II type (SG Pbcn, N. 60, Z= 4), and orthorhombic α-Gd 2 S 3 -type (SG Pnma, N. 62, Z= 4). Moreover, a new orthorhombic Rh 2 O 3 -III (SG Pbca, N. 61, Z= 8) phase has been recently discovered, which is considered to be the high-pressure structure of corundum-type In 2 O 3 at ambient temperature.…”