A promising fabrication route to produce absorbing flexible photonic crystals is presented, which exploits self-assembly during the shear processing of multi-shelled polymer spheres. When absorbing material is incorporated in the interstitial space surrounding high-refractive-index spheres, a dramatic enhancement in the transmission edge on the short-wavelength side of the band gap is observed. This effect originates from the shifting optical field spatial distribution as the incident wavelength is tuned around the band gap, and results in a contrast up to 100 times better than similar but nonabsorbing photonic crystals. An order-of-magnitude improvement in strain sensitivity is shown, suggesting the use of these thin films in photonic sensors. © 2005 American Institute of Physics. ͓DOI: 10.1063/1.2032590͔ Synthesis of three-dimensional ͑3D͒ photonic crystals based on synthetic opals has been well developed over the past decade, 1-3 with a particular focus on in-filling with highrefractive-index media to create true 3D band gaps.1,4 However, the application of 3D photonic crystals has been restricted compared to the advanced technology built on twodimensional photonic crystals fabricated from patterned planar waveguides.5-7 Here we present an alternative approach to fabricating useful photonic crystals based on the extrusion self-assembly of low-contrast flexible photonic nanomaterials. Tuning of the band gaps with angle and strain is clearly observed in these films. However, as is typical in polymer-based photonic crystals, the dielectric nanostructures exhibit a low on/off contrast at the edges of the Bragg scattering peaks making their incorporation into sensors problematic. We show that by introducing an absorbing material into the surroundings of the polymer spheres ͑which is very easy to achieve in this process͒, the transmission contrast can be increased by a factor of Ͼ100, leading to prospective applications in compact vibration and thermal sensors. We analyze this behavior in terms of the optical field distribution on either side of the band gap, and show that absorbing 3D photonic crystals inherently improve on the performance of absorbing one-dimensional ͑1D͒ photonic crystals ͑Bragg mirrors͒.Our sample precursors consist of hard polystyrene ͑PS͒ cores, covered by a poly͑methylmethacrylate͒ ͑PMMA͒ interlayer, and a polyethylacrylate ͑PEA͒ shell. Self-assembly processes occur during the shearing by uniaxial compression of the precursor melt resulting in fcc crystallization of the PS-PMMA cores, with the soft PEA shell material filling the spaces between the PS-PMMA lattice sites thus forming an elastic film. Hence the ͑111͒ plane of the fcc lattice is parallel to the sample surface. A detailed description of the precursors and the manufacturing is reported elsewhere. 8 The final samples used here are disks with a diameter of 10 cm and a thickness of around 250 m ͓Fig. 1͑a͔͒.Angle-dependent reflection measurements were carried out to identify the final lattice pitch and average refractive index. Monoch...