2019
DOI: 10.1029/2018jb017015
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Low‐Frequency Induced Polarization of Porous Media Undergoing Freezing: Preliminary Observations and Modeling

Abstract: We investigate the thermal dependence of the complex conductivity of nine porous materials in the temperature range +20°C to −10 or −15°C. The selected samples include three soils, two granites, three clay-sands mixes, and one graphitic tight sandstone. A total of 12 experiments is conducted with one sample tested at three different salinities. Our goal is to use this database to extend the dynamic Stern layer polarization model in freezing conditions. We observe two polarization mechanisms, one associated wit… Show more

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Cited by 28 publications
(104 citation statements)
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References 69 publications
(108 reference statements)
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“…Below freezing conditions, the water content of the liquid water is changing with the temperature according to a freezing curve. Duvillard et al () and Coperey et al () used an exponential freezing curve for the volumetric water content θ ( T ) written as θ()T={()ϕθrexp()0.36emTTFTC+θr,TTFϕ,10.5emT>TF0.12em, which has the advantage to only require three parameters, T F (the liquidus or freezing point), T C (a characteristic temperature), and θ r (the residual water content).…”
Section: Complex Conductivity Of Rocksmentioning
confidence: 99%
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“…Below freezing conditions, the water content of the liquid water is changing with the temperature according to a freezing curve. Duvillard et al () and Coperey et al () used an exponential freezing curve for the volumetric water content θ ( T ) written as θ()T={()ϕθrexp()0.36emTTFTC+θr,TTFϕ,10.5emT>TF0.12em, which has the advantage to only require three parameters, T F (the liquidus or freezing point), T C (a characteristic temperature), and θ r (the residual water content).…”
Section: Complex Conductivity Of Rocksmentioning
confidence: 99%
“…Below freezing conditions, the water content of the liquid water is changing with the temperature according to a freezing curve. Duvillard et al (2018) and Coperey et al (2019) used an exponential freezing curve for the volumetric water content θ(T) written as…”
Section: Influence Of Temperature and Permafrostmentioning
confidence: 99%
“…The soil freezing curve can be related to the characteristics of the pore size distribution like the capillary pressure curve (Spans & Baker, ). In freezing conditions and accounting for the salt segregation effect, the electrical conductivity of the porous material is (Coperey et al, ) σ()T=σ(T0)[]1+αTTT0, where m (dimensionless) corresponds to the porosity exponent of Archie's law and σ ( T 0 ) denotes the conductivity (in S/m) at the reference temperature T 0 (=25 °C). While not apparent in equation , this model comprises both a conductivity contribution in the pore space and a surface conductivity contribution associated with electrical double layer (and therefore related to the cation exchange capacity [CEC] of the material).…”
Section: Electrical Conductivity Versus Temperaturementioning
confidence: 99%
“…The soil freezing curve can be related to the characteristics of the pore size distribution like the capillary pressure curve (Spans & Baker, 1996). In freezing conditions and accounting for the salt segregation effect, the electrical conductivity of the porous material is (Coperey et al, 2019)…”
Section: Electrical Conductivity Versus Temperaturementioning
confidence: 99%
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