2022
DOI: 10.1039/d2ta04935j
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Low-energy intralayer phonon assisted carrier recombination in Z-scheme van der Waals heterostructures for photocatalysis

Abstract: Establishing the coupling mechanism of hot carriers and phonons is at the heart of nanoelectronics and photocatalyst of vdW heterostructures. Herein, via ab initio simulations, we endeavor to examine the...

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Cited by 10 publications
(4 citation statements)
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“…随着石墨烯的制备及其优异性能的发现, 二 维(2D)材料受到人们的广泛关注 [1,2] . 许多二维材 料被预测并通过实验合成, 包括过渡金属二硫族化 物 [3][4][5][6][7] 、过渡金属二卤族化物 [8] 、硼烯 [9][10][11][12][13][14] 、磷烯 [15][16][17][18] 、 MnBi 2 Te 4 [19] 、MA 2 Z 4 家族 [20][21][22] 等材料. 它们诱人 的应用前景及其新颖的物理和化学性质, 为设计和 制备新型材料和器件的实验工作提供了不竭的动 力.…”
Section: 引 言unclassified
“…随着石墨烯的制备及其优异性能的发现, 二 维(2D)材料受到人们的广泛关注 [1,2] . 许多二维材 料被预测并通过实验合成, 包括过渡金属二硫族化 物 [3][4][5][6][7] 、过渡金属二卤族化物 [8] 、硼烯 [9][10][11][12][13][14] 、磷烯 [15][16][17][18] 、 MnBi 2 Te 4 [19] 、MA 2 Z 4 家族 [20][21][22] 等材料. 它们诱人 的应用前景及其新颖的物理和化学性质, 为设计和 制备新型材料和器件的实验工作提供了不竭的动 力.…”
Section: 引 言unclassified
“…42 A room-temperature ammonia gas sensor has been developed based on a thin film of CsPbBr 3 ternary bromide. 43 Despite numerous studies on the interaction of various gas molecules with low dimensional materials, 44–46 the number of such works on ternary nitrides is small. For instance, a III-nitride-based heterostructure has demonstrated high sensitivity to hydrogen and unsaturated hydrocarbons.…”
Section: Introductionmentioning
confidence: 99%
“…15,16 A Z-type heterostructure, which inherits the same band arrangement as type-II heterostructures, is a heterostructure material with great potential for photocatalysis. 17 Different from a type-II heterostructure, the unique carrier transfer and recombination pathway between the two components of the Zscheme heterostructure facilitate photogenerated electron transfer between valence and conduction bands and the recombination of the photogenerated electron-holes between layers. 18,19 In addition, by combining a narrow-band semiconductor with a Z-scheme heterostructure method, the dilemma that a single-component photocatalyst cannot simultaneously achieve a strong redox capacity and light response range can be solved.…”
Section: Introductionmentioning
confidence: 99%