Low cost and efficient synthesis of magnetic iron oxide/activated sericite nanocomposites for rapid removal of methylene blue and crystal violet dyes

Abstract

Activated sericite was used as a solid matrix for control over the size of iron oxide nanoparticles (NPs). The activation of sericite was achieved by undergoing thermal, acid and salt treatments. Different weight ratios (w.r.) of iron oxide to activated sericite were prepared by varying the amount of iron oxide. X-ray diffraction (XRD) patterns illustrated a decrease in the intensity of sericite peaks by increasing the amount of iron oxide. High resolution-transmission electron microscopy (HR-TEM) analysis showed the formation of highly distributed quasi-spherical iron oxide NPs with average diameter of about 3.56-7.78 nm. The formation of mesoporous iron oxide NPs on the surface and edge of the activated sericite surface were also observed under Field emission scanning electron microscopy (FESEM). Vibration sample magnetometer (VSM) measurement revealed the nanocomposites (NCs) with saturation magnetization of about 2.17-8.12 emu•g−1. Brunauer-Emmett-Teller (BET) surface area analysis revealed the specific surface area of NCs between 79.4 and 161.5 m2•g−1. Fourier transform infrared (FTIR) spectra showed non-bond chemical interaction between the iron oxide and rigid silicate layers. Ultraviolet-visible (UV-vis) diffuse reflectance spectroscopy confirms that the material has band gap energy of about 2.55 eV. The NC with w.r. of 1:3 (iron oxide to activated sericite) showed the best performance with high specific surface area and sufficient magnetization for easy magnetic separation. The selected NC showed maximum removal efficiency over 99% for methylene blue and crystal violet dyes within 20 min.

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“…Humic acid, coated on the surface of magnetite as a sorbent, is an environmentally friendly material, and the structure of the magnetite core, with a humic acid shell, has better adsorption performance in an acid condition [ 81 ]. Other surface modifiers, such as oleic acid [ 89 ], functionalized chitosan [ 85 , 86 ], polyacrylic acid [ 40 ], lignosulfonate [ 84 ], and activated sericite clay [ 98 ], to some extent, could enhance the dispersion of magnetic nanocomposites, because they are widely spaced. In this way, the size of the nanocomposites can be controlled on a small scale, lower than 10 nm.…”

Advanced Materials for Societal Implementation

“…Humic acid, coated on the surface of magnetite as a sorbent, is an environmentally friendly material, and the structure of the magnetite core, with a humic acid shell, has better adsorption performance in an acid condition [81]. Other surface modifiers, such as oleic acid [89], functionalized chitosan [85,86], polyacrylic acid [40], lignosulfonate [84], and activated sericite clay [98], to some extent, could enhance the dispersion of magnetic nanocomposites, because they are widely spaced. In this way, the size of the nanocomposites can be controlled on a small scale, lower than 10 nm.…”