Foams
in the oil and gas industry have been used as divergent fluids
to attenuate the fluid channeling in high-permeability zones. Commonly,
foams are generated using a surfactant solution in high-permeability
reservoirs, which exhibit stability problems. Therefore, the main
objective of this study is to stabilize the foams by the addition
of modified silica nanoparticles, varying the surface acidity and
polarity for natural gas flooding in tight gas-condensated reservoirs.
Four types of modified silica-based nanoparticles with varying surface
acidity and polarity (coated with vacuum residue) were synthesized
and evaluated using surfactant adsorption. The basic nanoparticles
exhibited a greater adsorption capacity of the surfactant, reaching
an adsorbed amount of approximately 200 mg of surfactant per gram
of nanoparticles, and Type I adsorption behavior. Foams were generated
and evaluated based on their stability using two routes, namely, (1)
with mechanical agitation and (2) methane flooding, to determine the
optimal concentration of nanoparticles to be used. In both scenarios,
foam height was monitored against time, and the half-life of the foam
was established. The nanofluid prepared using a surfactant solution
and 500 mg/L of basic nanoparticles reached a half-life 41% greater
than that of the fluid that does not contain nanoparticles. In addition,
a core flooding test was performed to evaluate the generation and
perdurability of the foam (with and without nanoparticles) by methane
flooding and the mobility reduction at typical reservoir conditions
(confinement and pore pressure of 5200 and 1200 psi, respectively,
and temperature of 100 °C). The porous medium was obtained from
a tight gas-condensate reservoir, and it has an absolute permeability
of 65.1 mD and a porosity of 7%. The oil recovery with methane injection
was about 52%; with foam injection, an additional 10% was obtained,
and an 18% additional recovery was reached with the injection of foam
and nanoparticles.