A risk-averse preview-based Q-learning planner is presented for navigation of autonomous vehicles. To this end, the multi-lane road ahead of a vehicle is represented by a finitestate non-stationary Markov decision process (MDP). A risk assessment unit module is then presented that leverages the preview information provided by sensors along with a stochastic reachability module to assign reward values to the MDP states and update them as scenarios develop. A sampling-based riskaverse preview-based Q-learning algorithm is finally developed that generates samples using the preview information and reward function to learn risk-averse optimal planning strategies without actual interaction with the environment. The risk factor is imposed on the objective function to avoid fluctuation of the Q values, which can jeopardize the vehicle's safety and/or performance. The overall hybrid automaton model of the system is leveraged to develop a feasibility check unit module that detects unfeasible plans and enables the planner system to proactively react to the changes of the environment. Theoretical results are provided to bound the number of samples required to guarantee -optimal planning with a high probability. Finally, to verify the efficiency of the presented algorithm, its implementation on highway driving of an autonomous vehicle in a varying traffic density is considered.