Long-Lived Charge-Separated States in ZnS/Na-MOR Zeolite upon trans-Stilbene Adsorption
Pedro H. M. Andrade,
Matthieu Hureau,
Anne-Sophie Mamede
et al.
Abstract:Electron transfer (ET) processes are of fundamental importance
in many photochemical processes in biological and chemical systems.
Here, semiconductor nanoparticles of ZnS (as electron relay) and trans-stilbene molecules (t-St) (as electron
donor), both confined within the porous volume of mordenite (MOR),
are combined to mimic photosynthetic processes. ZnS nanoparticles
were synthesized by cationic exchange between the counterion of the
zeolite and ZnS precursors in solution. The characterization of the
ZnS/N… Show more
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