Discovery of ferroelectricity in HfO2 has
sparked a
lot of interest in its use in memory and logic due to its CMOS compatibility
and scalability. Devices that use ferroelectric HfO2 are
being investigated; for example, the ferroelectric field-effect transistor
(FEFET) is one of the leading candidates for next generation memory
technology, due to its area, energy efficiency and fast operation.
In an FEFET, a ferroelectric layer is deposited on Si, with an SiO2 layer of ∼1 nm thickness inevitably forming at the
interface. This interfacial layer (IL) increases the gate voltage
required to switch the polarization and write into the memory device,
thereby increasing the energy required to operate FEFETs, and makes
the technology incompatible with logic circuits. In this work, it
is shown that a Pt/Ti/thin TiN gate electrode in a ferroelectric Hf0.5Zr0.5O2 based metal-oxide-semiconductor
(MOS) structure can remotely scavenge oxygen from the IL, thinning
it down to ∼0.5 nm. This IL reduction significantly reduces
the ferroelectric polarization switching voltage with a ∼2×
concomitant increase in the remnant polarization and a ∼3×
increase in the abruptness of polarization switching consistent with
density functional theory (DFT) calculations modeling the role of
the IL layer in the gate stack electrostatics. The large increase
in remnant polarization and abruptness of polarization switching are
consistent with the oxygen diffusion in the scavenging process reducing
oxygen vacancies in the HZO layer, thereby depinning the polarization
of some of the HZO grains.