Multiple scattering of waves leads to many peculiar phenomena such as complete band gaps in periodic structures and wave localization in disordered media. Within a band gap excitations are evanescent; when localized they remain confined in space until dissipated. Here we report acoustic band gap and localization in a 2D system of air-cylinders in water. Exact numerical calculations reveal the unexpected result that localization is relatively independent of the precise location or organization of the scatterers. Localization occurs within a finite region of frequencies, coincident with the complete band gap predicted by a conventional band structure calculation for a periodic lattice of scatterers. Inside the gap or localization regime, a previously uninvestigated stable collective behavior of the cylinders appears. Multiple scattering of waves is responsible for a wide range of fascinating phenomena 1,2 . This includes twinkling light in the evening sky, modulation of ambient sound at the ocean surfaces 3 , and acoustic scintillation of turbulence 4 . On smaller scales, phenomena such as random lasers 5 and electron transport in impure solids 6 are also explained by multiple scattering. Under appropriate conditions, multiple scattering leads to photonic or acoustic band gaps in classical wave propagation in periodic structures 7,8 , and to the unusual phenomenon of wave localization, a concept introduced by