Lithium, titanium and vanadium dithiocarboxylatesElectronic supplementary information (ESI) available: additional crystallographic details. See http://www.rsc.org/suppdata/dt/b2/b210691d/

Ives, Christina; Fillis, Elaine L.; Hagadorn, John R.

doi:10.1039/b210691d

Cited by 7 publications

(5 citation statements)

References 14 publications

(8 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…To generate the dithiocarboxylate copper complexes, (Et 2 O) 2 Li [S 2 C(2,6-(Mes) 2 C 6 H 3 )] (Mes = 2,4,6-Me 3 C 6 H 2 ) 11 and (thf ) 2 Li [S 2 C(2,6-(Trip) 2 C 6 H 3 )] (Trip = 2,4,6-iPr 3 C 6 H 2 ) 11 4 in the presence of one equivalent of PEt 3 both yielded Cu[S 2 C(2,6-Trip) 2 C 6 H 3 ](PEt 3 ) 2 , 5, in good yield, eqn (3).…”

Section: Dithiocarboxylate Complexesmentioning

confidence: 99%

Copper(i) clusters with bulky dithiocarboxylate, thiolate, and selenolate ligands

2016

View full text Add to dashboard Cite

The coordination chemistry of copper has interest due to its use in biological systems as well as for photochemical and medicinal properties. We report the coordination chemistry of copper(i) complexes using terphenyl-based dithiocarboxylate, thiolate, and selenolate ligands. The number of metal ions of the resulting complexes can be tuned by varying the steric properties of the terphenyl ligands, changing the starting material, as well as adding PEt3. In addition, the steric crowding of the terphenyl ligand leads to varying reactivity. For example, while the reaction of carbon disulfide with [Cu(2,6-(Ph)2C6H3)]2 results in an insertion into the copper-carbon bond, no reaction occurs with [Cu(2,4,6-(Mes)2C6H3)], Mes = 2,4,6-Me3C6H2, or [Et3PCu(2,4,6-(Mes)2C6H2)2C6H3]. The synthesis and characterization of new copper(i) complexes using NMR and IR spectroscopy, as well as X-ray crystallography is described.

show abstract

Section: Dithiocarboxylate Complexesmentioning

confidence: 99%

Copper(i) clusters with bulky dithiocarboxylate, thiolate, and selenolate ligands

2016

View full text Add to dashboard Cite

show abstract

“…Special attention has therefore been devoted to their structure, which can sometimes be controlled by an appropriate method of synthesis (Englich & Ruhlandt-Senge, 2000). The most common lithium thiolates are monomeric (Chadwick & Ruhlandt-Senge, 1998;Ives et al, 2003) or dimeric (Bjernemose et al, 2004;Komuro et al, 2004). However, trimeric (Ruhlandt-Senge et al, 1996;Niemeyer & Power, 1996), hexameric (Janssen et al, 1996) and polymeric forms (Ruth et al, 2005;Hampe et al, 2005) are also known.…”

Section: Commentmentioning

confidence: 99%

The first compound with an unusual type of anion, [Li(SR)₂]^–: bis(μ₂-aqua-d₂)tetrakis(aqua-d₂)dilithium(I) bis[bis(tri-tert-butoxysilanethiolato-κ²O,S)lithate(I)] dihydrate-d₂

Kloskowska

Chojnacki

Wojnowski

et al. 2006

Acta Crystallogr C Cryst Struct Commun

View full text Add to dashboard Cite

The title complex, [Li2(D2O)6][Li(C9H27SSiO3)2]2.2D2O, is the first compound with an S-M bond (M = alkali metal) within an unusual type of lithate anion, [Li(SR)2]- {where R is Si[OC(CH3)3]3}. There is a centre of symmetry located in the middle of the Li2O2 ring of the cation. All Li atoms are four-coordinate, with LiO4 (cations) and LiO2S2 (anions) cores. The singly charged [Li(SR)2]- anions are well separated from the doubly charged [Li2(D2O)6]2+ cations; the distance between Li atoms from differently charged ions is greater than 5 A. Both ion types are held within an extended network of O-D...O and O-D...S hydrogen bonds.

show abstract

“…65 Interesting dithiocarboxylates have been reported, both the paramagnetic Ti(III) compound [2,6-Mes 2 C 6 H 3 CS 2 ]TiCl 2 (thf) 2 and the diamagnetic Ti(IV) complex, [2,6-Trip 2 C 6 H 3 CS 2 ] 2 TiCl 2 (py), with authenticating structures for each. 66 Conjugates of Zr(IV) complexes and peptide nucleic acids catalyse sequence selective hydrolysis of linear DNA. 67…”

Section: Oxides and Other Binary And Related Compoundsmentioning

confidence: 99%

11 Titanium, zirconium and hafnium

Cotton¹

2004

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem.

View full text Add to dashboard Cite

It is again easier to identify areas of activity than to point towards specific advances, with active research dominated by organometallics with a view to catalytic activity; alkoxides, amides and related compounds that can afford thin films of compounds like TiO 2 ; and TiO 2 itself. Lesser delights include the identification of the TBPY [ZrCl 5 ] 2 anion and the giant titanium polyoxotungstate with four tri-Ti IV -1,2,3-substituted a-Dawson substructures.

show abstract

Lithium, titanium and vanadium dithiocarboxylatesElectronic supplementary information (ESI) available: additional crystallographic details. See http://www.rsc.org/suppdata/dt/b2/b210691d/

Cited by 7 publications

References 14 publications

Copper(i) clusters with bulky dithiocarboxylate, thiolate, and selenolate ligands

Copper(i) clusters with bulky dithiocarboxylate, thiolate, and selenolate ligands

The first compound with an unusual type of anion, [Li(SR)₂]^–: bis(μ₂-aqua-d₂)tetrakis(aqua-d₂)dilithium(I) bis[bis(tri-tert-butoxysilanethiolato-κ²O,S)lithate(I)] dihydrate-d₂

11 Titanium, zirconium and hafnium

Contact Info

Product

Resources

About

Lithium, titanium and vanadium dithiocarboxylatesElectronic supplementary information (ESI) available: additional crystallographic details. See http://www.rsc.org/suppdata/dt/b2/b210691d/

Cited by 7 publications

References 14 publications

Copper(i) clusters with bulky dithiocarboxylate, thiolate, and selenolate ligands

Copper(i) clusters with bulky dithiocarboxylate, thiolate, and selenolate ligands

The first compound with an unusual type of anion, [Li(SR)2]–: bis(μ2-aqua-d2)tetrakis(aqua-d2)dilithium(I) bis[bis(tri-tert-butoxysilanethiolato-κ2O,S)lithate(I)] dihydrate-d2

11 Titanium, zirconium and hafnium

Contact Info

Product

Resources

About

The first compound with an unusual type of anion, [Li(SR)₂]^–: bis(μ₂-aqua-d₂)tetrakis(aqua-d₂)dilithium(I) bis[bis(tri-tert-butoxysilanethiolato-κ²O,S)lithate(I)] dihydrate-d₂