Lithium‐Ion‐Based Electrochemical Energy Storage in a Layered Vanadium Formate Coordination Polymer

Anjana, P. K.; Babu, B. Rajesh; Shaijumon, Manikoth M.; Thirumurugan, A.

doi:10.1002/cplu.202000283

Cited by 3 publications

(2 citation statements)

References 74 publications

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“…Researchers and scientists are working on how to solve this problem and enhance Li-ion battery properties. 85,86 Typical Li-ion batteries mainly consist of a positive (cathode) and a negative (anode) electrode. Figure 7 represents the structure of the Li-ion battery.…”

Section: Lithium-ion Batterymentioning

confidence: 99%

“…Some circumstances primarily cause this issue: Li anodes provide a safety risk due to their large surface areas, potential internal short circuits, and short‐term life cycle issues. Researchers and scientists are working on how to solve this problem and enhance Li‐ion battery properties 85,86 . Typical Li‐ion batteries mainly consist of a positive (cathode) and a negative (anode) electrode.…”

Section: Energy Storage Technologiesmentioning

confidence: 99%

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A comprehensive state‐of‐the‐art review of electrochemical battery storage systems for power grids

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Safaei

Zargar

et al. 2022

Intl J of Energy Research

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Summary As the world's population and living standards rise, energy suppliers will face increased electrical energy needs. Furthermore, the European Commission has established a goal to reduce fossil fuel use and greenhouse gas emissions in accordance with the Kyoto and Paris Protocols. As a result, governments are more likely to integrate renewable energy into their electricity grids. However, since renewable energy resources are intermittent, power grid systems confront considerable hurdles. By overcoming the intermittency of renewable energy resources, battery storage systems are one way to optimize load and demand. Many studies show that the stored energy can be used in high demand. This may reduce the cost of production in the long run. Energy storage systems can also provide voltage and frequency regulation to power systems when connected to the transmission and/or distribution lines. The application and benefits of battery storage devices in electricity grids are discussed in this study. The pros and disadvantages of various electrochemical batteries, including their structure, energy capacity, and application areas, are compared and summarized and their benefits and drawbacks are included. Finally, the research demonstrates how electrochemical battery technologies and power grids have collaborated.

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Section: Lithium-ion Batterymentioning

confidence: 99%

Section: Energy Storage Technologiesmentioning

confidence: 99%

A comprehensive state‐of‐the‐art review of electrochemical battery storage systems for power grids

Solyalı

Safaei

Zargar

et al. 2022

Intl J of Energy Research

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Materials, electrodes and electrolytes advances for next-generation lithium-based anode-free batteries

Pal

Zhang

Babu

et al. 2022

Oxford Open Materials Science

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The high volumetric stack energy density (∼ 750Wh L−1) is a must for grasping the practical application of electric vehicles with more than 100 km per day driving range. Such achievement requires significant advances in state-of-the-art battery technologies. The anode-free, derived from the metal-battery concept, germinates as one of the future potential battery configurations due to the highest, nearly theoretical gravimetric and volumetric energy density. Thus, moving from the graphite-based anode, where lithium is stored as ions, to anode-free cells, wherein lithium is plated as metal, can change the scenario of the electrochemical energy storing devices both in terms of energy density and fundamental mechanism. Although an anode-free battery theoretically provides higher stack energy density than a Li-ion battery, current developments are still underoptimized as these can barely hold for several cycles at room temperature due to the absence of an active lithium reservoir and still severe losses at the anode side. Hence electrolyte engineering with suitable electrode material choice is highly desirable and extremely challenging in realizing next-generation anode-free batteries. Herein, we summarize the current developments and achievements in the direction of anode-free batteries. Central emphasis is set on electrolyte chemistries that should on one hand allow for high-efficiency initial nucleation, followed by subsequent electrodeposition and electrodissolution of lithium metal, while also forming stable anodic interphases with the high energy cathode materials currently in use. We also prospect for better batteries with higher energy density beyond the present status.

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Recent reports on vanadium based coordination polymers and MOFs

Gupta¹

2022

Reviews in Inorganic Chemistry

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Coordination polymers (CP) and metal-organic frameworks (MOF) have become a topic of immense interest in this century primarily because of the structural diversity that they offer. This structural diversity results in their multifaceted utility in various fields of science and technology such as catalysis, medicine, gas storage or separation, conductivity and magnetism. Their utility inspires a large variety of scientists to engage with them in their scientific pursuit thus creating a buzz around them in the scientific community. Metals capable of forming CPs and MOFs are primarily transition metals. Among them vanadium-based CPs and MOFs demand detailed discussion because of the unique nature of vanadium which makes it stable in many oxidation states and coordination number. Vanadium’s versatility imparts additional structural marvel and usefulness to these CPs and MOFs.

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Lithium‐Ion‐Based Electrochemical Energy Storage in a Layered Vanadium Formate Coordination Polymer

Cited by 3 publications

References 74 publications

A comprehensive state‐of‐the‐art review of electrochemical battery storage systems for power grids

A comprehensive state‐of‐the‐art review of electrochemical battery storage systems for power grids

Materials, electrodes and electrolytes advances for next-generation lithium-based anode-free batteries

Recent reports on vanadium based coordination polymers and MOFs

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