LiSnOS/gel polymer hybrid electrolyte for the safer and performance-enhanced solid-state LiCoO2/Li lithium-ion battery

Kuo, Dong‐Hau; Lo, Roger Yu; Hsueh, Tien Hsiang; Jan, Der-Jun; Su, Chi-Hung

doi:10.1016/j.jpowsour.2019.05.010

Cited by 13 publications

(11 citation statements)

References 29 publications

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“…Currently, the layered cathode materials for lithium batteries include LiNi 0.8 Co 0.1 Mn 0.1 O 2 , [ 78–80 ] LiMnO 2 , [ 81–82 ] LiCoO 2 , [ 83–85 ] and LiFePO 4 [ 86–90 ] (LFP), which are ground with acetylene black and polymer binders, and coated on the current collector to prepare the cathodes. The randomly assembled cathodes generate high‐tortuous and discontinuous conductive pathways for ions and electrons, resulting in low‐rate capabilities.…”

Section: Low‐tortuous Cathodes For Metallic Lithium Batteriesmentioning

confidence: 99%

Tortuosity Modulation toward High‐Energy and High‐Power Lithium Metal Batteries

Shi

Zhang

et al. 2021

Advanced Energy Materials

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Section: Low‐tortuous Cathodes For Metallic Lithium Batteriesmentioning

confidence: 99%

Tortuosity Modulation toward High‐Energy and High‐Power Lithium Metal Batteries

Shi

Zhang

et al. 2021

Advanced Energy Materials

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“…The Pd 60 Ni 40 ratio was the most efficient and stable, generating a maximum power density of 1.12 mWcm −2 e. (Figure 12a-d). [168] Alba Garzón Manjón et al used magnetron sputtering to prepare Cr-Mn-Fe-Co-Ni HEAs in different ionic liquids, resulting in eight colloidal suspensions of complex solid solution nanoparticles (CSSNPs). These nanoparticles have a narrow size distribution (ranging from 1.3 ± 0.1 nm to 2.6 ± 0.3 nm) and exhibit varying crystallinity (amorphous, face-centered cubic, or body-centered cubic).…”

Section: Sputteringmentioning

confidence: 99%

Bimetallic Nanoalloy Catalysts for Green Energy Production: Advances in Synthesis Routes and Characterization Techniques

Ashraf

Liu

Wei

et al. 2023

Small

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Bimetallic Nanoalloy catalysts have diverse uses in clean energy, sensing, catalysis, biomedicine, and energy storage, with some supported and unsupported catalysts. Conventional synthetic methods for producing bimetallic alloy nanoparticles often produce unalloyed and bulky particles that do not exhibit desired characteristics. Alloys, when prepared with advanced nanoscale methods, give higher surface area, activity, and selectivity than individual metals due to changes in their electronic properties and reduced size. This review demonstrates the synthesis methods and principles to produce and characterize highly dispersed, well‐alloyed bimetallic nanoalloy particles in relatively simple, effective, and generalized approaches and the overall existence of conventional synthetic methods with modifications to prepare bimetallic alloy catalysts. The basic concepts and mechanistic understanding are represented with purposely selected examples. Herein, the enthralling properties with widespread applications of nanoalloy catalysts in heterogeneous catalysis are also presented, especially for Hydrogen Evolution Reaction (HER), Oxidation Reduction Reaction (ORR), Oxygen Evolution Reaction (OER), and alcohol oxidation with a particular focus on Pt and Pd‐based bimetallic nanoalloys and their numerous fields of applications. The high entropy alloy is described as a complicated subject with an emphasis on laser‐based green synthesis of nanoparticles and, in conclusion, the forecasts and contemporary challenges for the controlled synthesis of nanoalloys are addressed.

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“…The transport of lithium ions in the polymer depends largely on the free movement of the chains in the amorphous phase. Therefore, as illustrated in Figure 7, the main purpose of introducing ceramic modifiers, whether active or inert, is to reduce the crystallinity of the polymer [21,76, 130–139] . For instance, in the work of Zhao et al., after adding LGPS (Li 10 GeP 2 S 12 ) powders into the PEO‐based electrolyte, the glass transition temperature ( T g ) reduced to −41.6∼−41.3 °C from −39.6 °C.…”

Section: Ceramic/polymer Composite Solid‐state Electrolytementioning

confidence: 99%

“…polymer. [21,76,[130][131][132][133][134][135][136][137][138][139] For instance, in the work of Zhao et al, after adding LGPS (Li 10 GeP 2 S 12 ) powders into the PEO-based electrolyte, the glass transition temperature (T g ) reduced to À 41.6À 41.3°C from À 39.6°C. The melting temperature (T m2 ) dropped from 66.5°C to 57.8~59.9°C.…”

Section: Zero-dimensional Ceramic Materials/polymer Compositementioning

confidence: 99%

Designing Ceramic/Polymer Composite as Highly Ionic Conductive Solid‐State Electrolytes

Qian

Chen

et al. 2020

Batteries & Supercaps

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The design and fabrication of solid‐state electrolytes (SSEs) with high ionic conductivity is the most crucial obstacle for all‐solid‐state lithium batteries (ASSLBs). However, though polymer SSEs have the advantages of effective interfacial contact, polymer ASSLBs have not been able to deliver performance comparable to conventional lithium‐ion batteries (LIBs) due to slow ion transport within the polymer framework. In contrast, the high inherent ionic conductivity of ceramic SSEs is limited by the poor electrolyte/electrode interfacial contact. Therefore, the concept of ceramic/polymer composite electrolytes (C/PCEs) was proposed to combine the advantages of these two electrolytes and simultaneously overcome their weaknesses. This work reviews the recent progress in C/PCEs development according to the morphology of the ceramic components in C/PCEs. In this review, we investigate the inherent relationship between the structures of C/PCEs and the performance of the resultant SSEs, and subsequently conclude some general C/PCE design principles for future SSEs.

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LiSnOS/gel polymer hybrid electrolyte for the safer and performance-enhanced solid-state LiCoO2/Li lithium-ion battery

Cited by 13 publications

References 29 publications

Tortuosity Modulation toward High‐Energy and High‐Power Lithium Metal Batteries

Tortuosity Modulation toward High‐Energy and High‐Power Lithium Metal Batteries

Bimetallic Nanoalloy Catalysts for Green Energy Production: Advances in Synthesis Routes and Characterization Techniques

Designing Ceramic/Polymer Composite as Highly Ionic Conductive Solid‐State Electrolytes

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