LiSn2(PO4)3-based polymer-in-ceramic composite electrolyte with high ionic conductivity for all-solid-state lithium batteries

Ahmed, Shadab Ali; Pareek, Tanvi; Dwivedi, Sushmita; Badole, Manish; Kumar, Sunil

doi:10.1007/s10008-020-04783-z

Cited by 22 publications

(8 citation statements)

References 52 publications

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“…Ramkumar Balasubramaniam and his coworkers demonstrated the performance of the solid‐state battery that constitutes the composite electrolyte, NCM811 (nickel 80%, cobalt 10%, and manganese 10%), and lithium metal electrodes. They successfully enhanced the discharge ability of this cell assembly from 163 to 198 mAh g −1 from the modification of LiNbO 3 over NCM811 which improved the reversibility and capability rate of the device 257 …”

Section: Electrochemical Characterizationmentioning

confidence: 99%

Potential electrolytes for solid state batteries and its electrochemical analysis—A review

Zulfiqar

Abbas

et al. 2023

Energy Storage

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The main purpose of this review is to present comprehensive research on all solid‐state electrolytes in a single frame. In next‐generation rechargeable solid‐state batteries, the solid‐state electrolytes are well known for their thermal stability, ionic conduction, and electrochemical stability. Therefore, in scientific societies, the development of potential solid‐state electrolytes become a trending debate to enhance their cycling stability and electrochemical properties. Here, the recent development of all solid electrolytes (such as ceramic and structure‐based electrolytes) to enhance their electrochemical properties is summarized. From previous studies, the installation of solid electrolytes is hindered by the following factors electrode‐electrolyte interface, dendrite growth, and discharge capacity as well as its solutions are discussed. Additionally, advanced electrochemical characterization techniques such as electrochemical impedance spectroscopy, cyclic voltammetry, and galvanostatic charging and discharging used to evaluate the electrochemical behavior of electrolytes in the solid frame are summarized for the first time. Moreover, an up‐to‐date article on battery performance with potential electrolytes and some future perspectives also give a vivid image of the pragmatic applications of these batteries at the commercial level.

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Section: Electrochemical Characterizationmentioning

confidence: 99%

Potential electrolytes for solid state batteries and its electrochemical analysis—A review

Zulfiqar

Abbas

et al. 2023

Energy Storage

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“…For example, Lu et al have successfully prepared carbon nanofibers uniformly dispersed with CoSn intermetallic alloy nanoparticles (CoSn/ CNFS), which have demonstrated a RT capacity of 1112mAh/g [254][255][256]. Cu 6 Sn 5 is also one of the Sn alloy electrode materials of interest [257][258][259][260]. Andrew et al investigated the performance of Cu 6 Sn 5 and surface silver-plated Cu 6 Sn 5 at both RT and LT. At RT (30 °C), Cu 6 Sn 5 has a theoretical capacity of 225mAh/g.…”

Section: Alloy Based Cathodementioning

confidence: 99%

“…have successfully prepared carbon nanofibers uniformly dispersed with CoSn intermetallic alloy nanoparticles (CoSn/CNFS), which have demonstrated a RT capacity of 1112mAh/g [254–256]. Cu 6 Sn 5 is also one of the Sn alloy electrode materials of interest [257–260]. Andrew et al.…”

Section: Alloy Based Electrodementioning

confidence: 99%

A review on electrode and electrolyte for lithium ion batteries under low temperature

Zheng

Liu

et al. 2023

Electroanalysis

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Under low temperature (LT) conditions (−80 °C∼0 °C), lithium‐ion batteries (LIBs) may experience the formation of an extensive solid electrolyte interface (SEI), which can cause a series of detrimental effects such as Li+ deposition and irregular dendritic filament growth on the electrolyte surface. These issues ultimately lead to the degradation of the LT performance of LIBs. As a result, new electrode/electrolyte materials are necessary to address these challenges and enable the proper functioning of LIBs at LT. Given that most electrochemical reactions in lithium‐ion batteries occur at the electrode/electrolyte interface, finding solutions to mitigate the negative impact caused by SEI is crucial to improve the LT performance of LIBs. In this article, we analyze and summarize the recent studies on electrode and electrolyte materials for low temperature lithium‐ion batteries (LIBs). These materials include both metallic materials like tin, manganese, and cobalt, as well as non‐metallic materials such as graphite and graphene. Modified materials, such as those with nano or alloying characteristics, generally exhibit better properties than raw materials. For instance, Sn nanowire‐Si nanoparticles (SiNPs−In‐SnNWs) and tin dioxide carbon nanotubes (SnO2@CNT) have faster Li+ transport rates and higher reversible capacity at LT. However, it′s important to note that when operating under LT, the electrolyte may solidify, leading to difficulty in Li+ transmission. The compatibility between the electrolyte and electrode can affect the formation of the solid electrolyte interphase (SEI) and the stability of the electrode/electrolyte system. Therefore, a good electrode/electrolyte system is crucial for successful operation of LIBs at LT.

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“…Notably, there are signicant variations in both the resulting polarization overpotential and susceptibility to fracture, highlighting the need for an optimally designed hybrid structure for ideal material and transport properties. A multitude of other research with conductive oxides as llers have also been conducted with garnets, 25,28,30,81,[129][130][131] NASICONs, 31,[132][133][134][135] LISI-CONs, 136 and perovskites. 34,[137][138][139] In comparison to the oxide-polymer hybrid electrolytes, there is only a limited amount of work on sulde-polymer composites available.…”

Section: Conductive Inorganic Component: Importance Of the 3d Networkmentioning

confidence: 99%

Polymer-based hybrid battery electrolytes: theoretical insights, recent advances and challenges

et al. 2021

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LiSn2(PO4)3-based polymer-in-ceramic composite electrolyte with high ionic conductivity for all-solid-state lithium batteries

Cited by 22 publications

References 52 publications

Potential electrolytes for solid state batteries and its electrochemical analysis—A review

Potential electrolytes for solid state batteries and its electrochemical analysis—A review

A review on electrode and electrolyte for lithium ion batteries under low temperature

Polymer-based hybrid battery electrolytes: theoretical insights, recent advances and challenges

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