Liquid-liquid extractions with metal diethyldithiocarbamates as reagents

Bajo, S.

doi:10.1007/bf02037321

Journal of Radioanalytical and Nuclear Chemistry, Articles

1985

DOI: 10.1007/bf02037321

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Liquid-liquid extractions with metal diethyldithiocarbamates as reagents

S. Bajo¹

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Cited by 9 publications

References 65 publications

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Complexation of trialkyllead with diethyldithiocarbamate

Branica

1994

Electroanalysis

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Sodium salt of diethyldithiocarbamate (NaDDC) is one of the best-known organic reagents which form extractable chelates with many metal ions. Although many data on the characteristics of metal-DDC complexes have been published, no information about organometal complexes is available. In this work, the calculation of stability constants of trialkyllead-DDC complexes is described and their values are measured by electrochemical techniques. Obtained values are (1.9 2 0.7) x lo6 for (C2H,)3PbDDC and (3.1 2 1.5) X lo5 for (CH,),PbDDC. The application of these constants for the prediction of trialkylleads behavior during complexometric extraction from water to organic solvent is discussed.

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Complexation of trialkyllead with diethyldithiocarbamate

Branica

1994

Electroanalysis

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Selectivity of hybrid voltammetric determinations

Lubuda

Vaníčková

1996

Electroanalysis

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The selectivity of solvent extraction voltammetry and ion-exchange voltammetry hybrid procedures has been investigated. The equations for the prediction of the selectivity value according to the extraction constants or distribution coefficients of the analyte and interfering component were obtained. Their verification and application at the determination of trace metals in model and real samples are presented.

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General method for the liquid-liquid extraction of molybdenum and its application to neutron activation analysis

Bajo

Tobler

Wytténbach

1993

Fresenius J Anal Chem

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Liquid-liquid extractions with metal diethyldithiocarbamates as reagents

Cited by 9 publications

References 65 publications

Complexation of trialkyllead with diethyldithiocarbamate

Complexation of trialkyllead with diethyldithiocarbamate

Selectivity of hybrid voltammetric determinations

General method for the liquid-liquid extraction of molybdenum and its application to neutron activation analysis

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