Liquid Crystals of Carbon Nanotubes and Carbon Nanotubes in Liquid Crystals

Scalia, Giusy

doi:10.1002/9781118259993.ch10

Cited by 11 publications

(2 citation statements)

References 169 publications

(228 reference statements)

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“…14 The orientation of guest colloidal particles is switchable together with host LC molecules. Such switchable guest−host systems have been realized with gold NPs, 17 semiconductor quantum dots, 18 dichroic dyes, 19 carbon nanotubes, 20 graphene flakes, 21 metal nanorods, nanoplatelets, 22 and quantum rods. 23,24 NPs with proper alignment find applications in biology, materials science, and optoelectronics.…”

Section: Introductionmentioning

confidence: 99%

Electrically Switchable Anisometric Carbon Quantum Dots Exhibiting Linearly Polarized Photoluminescence: Syntheses, Anisotropic Properties, and Facile Control of Uniaxial Orientation

et al. 2022

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Carbon quantum dots (CQDs) have been extensively explored in diverse fields because of their exceptional features. The nanometric particles with photoluminescence (PL) benefit various optical and photonic applications. However, the majority of previous reports have mainly focused on either unpolarized or circular-polarized (CP) PL. Linearly polarized (LP) emission of CQDs is limited mainly because of their isometric shape and difficulties in macroscopic orientation control. Herein, we report syntheses of anisometric CQDs and facile control of the uniaxial orientation on a macroscopic scale, which results in linearly polarized photoluminescence (LP-PL). The anisometric CQDs are synthesized from rigid-rod-shaped precursors and evenly dispersed in the rod-like liquid crystal (LC) host. As-synthesized CQDs exhibit a PL quantum yield as high as 35% in chloroform. In addition to uniform alignment, facile directional switching of the elongated CQD is established by employing the electrical responsiveness of the CQD and host LC. Therefore, the dichroic photophysical properties of anisometric CQDs have been beneficially adopted for fabrications of polarization-sensitive and electrically switchable PL devices. Also, anisometric CQDs are embedded in polymer films with molecular orientational patterns and clearly recognized by LP-PL.

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Section: Introductionmentioning

confidence: 99%

Electrically Switchable Anisometric Carbon Quantum Dots Exhibiting Linearly Polarized Photoluminescence: Syntheses, Anisotropic Properties, and Facile Control of Uniaxial Orientation

et al. 2022

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“…Functional composite nanomaterials are widely spread in our everyday life. During the last few years, various composite materials attract substantial attention due to their advanced properties [1][2][3][4][5][6][7][8][9] that are usually inaccessible for the single component substances. According to definition, the composite materials are those made of at least two constituent compounds with significantly different physical and/or chemical properties that, when combined, might produce a smart resulting material with advanced characteristics different from the individual components under condition that individual components remain chemically separate and distinctive within the final composite structure.…”

Section: Introductionmentioning

confidence: 99%

Self-Assembling Behavior of Smart Nanocomposite System: Ferroelectric Liquid Crystal Confined by Stretched Porous Polyethylene Film

et al. 2020

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The control and prediction of soft systems exhibiting self-organization behavior can be realized by different means but still remains a highlighted task. Novel advanced nanocomposite system has been designed by filling of a stretched porous polyethylene (PE) film with pore dimensions of hundreds of nanometers by chiral ferroelectric liquid crystalline (LC) compound possessing polar self-assembling behavior. Lactic acid derivative exhibiting the paraelectric orthogonal smectic A* and the ferroelectric tilted smectic C* phases over a broad temperature range is used as a self-assembling compound. The morphology of nanocomposite film has been checked by Atomic Force Microscopy (AFM). The designed nanocomposite has been studied by polarizing optical microscopy (POM), differential scanning calorimetry (DSC), small and wide-angle X-ray scattering and broadband dielectric spectroscopy. The effect of a porous PE confinement on self-assembling, structural, and dielectric behavior of the chiral LC compound has been established and discussed. While the mesomorphic and structural properties of the nanocomposite are found not to be much influenced in comparison to that of a pure LC compound, the polar properties have been toughly suppressed by the specific confinement. Nevertheless, the electro-optic switching was clearly observed under applied electric field of low frequency (210 V, 19 Hz). The dielectric spectroscopy and X-ray results reveal that the helical structure of the ferroelectric liquid crystal inside the PE matrix is completely unwound, and the molecules are aligned along stretching direction. Obtained results demonstrate possibilities of using stretched porous polyolefins as promising matrices for the design of new nanocomposites.

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Carbon Nanotubes in Liquid Crystals: Fundamental Properties and Applications

Lisetski

Soskin

Lebovka

2015

Springer Proceedings in Physics

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The structure and properties of liquid crystalline suspensions filled by carbon nanotubes (CNTs) are critically reviewed. Special attention is paid to interactions between CNTs and molecules of the liquid crystals (LC), which lead to formation of ordered supramolecular structures. These structures, in turn, determine unique physical properties of LC + CNT suspensions, including electrical conductivity, dielectric permittivity, phase transitions, optical transmission, memory effects that can be used in electrooptic and optoelectronic devices, etc. Great variety of LC phases are considered as a host media, such as nematics, cholesterics, smectics of different types (including ferroelectrics), lyotropic, chromonic, ionic and hydrogen-bonded liquid crystals. Alongside multi-and single-walled carbon nanotubes, the suspensions can also contain the platelets of organoclays used for facilitation of CNT dispersing. Recent practical applications of LC + CNT suspensions and nanomaterials based thereon are also outlined.

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Liquid Crystals of Carbon Nanotubes and Carbon Nanotubes in Liquid Crystals

Cited by 11 publications

References 169 publications

Electrically Switchable Anisometric Carbon Quantum Dots Exhibiting Linearly Polarized Photoluminescence: Syntheses, Anisotropic Properties, and Facile Control of Uniaxial Orientation

Electrically Switchable Anisometric Carbon Quantum Dots Exhibiting Linearly Polarized Photoluminescence: Syntheses, Anisotropic Properties, and Facile Control of Uniaxial Orientation

Self-Assembling Behavior of Smart Nanocomposite System: Ferroelectric Liquid Crystal Confined by Stretched Porous Polyethylene Film

Carbon Nanotubes in Liquid Crystals: Fundamental Properties and Applications

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