Liquid Ammonia as a Solvent. III. The Solubility of Inorganic Salts at 25°

Hunt, Herschel; Boncyk, L.

doi:10.1021/ja01336a005

Cited by 37 publications

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“…Solubility values for twenty-six inorganic compounds and for three sets of mixed-salt pairs have been reported by Hunt and Boncyk (4). They claim to have checked their method against the vapor pressure method and to have found perfect agreement.…”

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confidence: 89%

Liquid ammonia research in 1933—A review

Watt¹

1934

J. Chem. Educ.

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the years which have elapsed since the publication of the early work of Franklin, Kraus, and Cady which pointed out the possibilities of liquid ammonia as a medium for the study of chemical phenomena, the attention of many chemists has been attracted by this somewhat unusual field of research. This widespread interest has not been confined to those who have furthered the work of Franklin in establishing an ammonia system of compounds, but workers in other fields have often had occasion to take advantage of some of the unusual properties of

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confidence: 89%

Liquid ammonia research in 1933—A review

Watt¹

1934

J. Chem. Educ.

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“…In this respect, the solubility of CsNH 2 in ammonia at low temperatures is orders of magnitude higher than these of e.g. LiNH 2 or NaNH 2 ; however only little information is available on the temperature dependence of the solubilities of these ammonobasic mineralizers towards ammonothermal conditions. In presence of zinc the formation of amidozincates as soluble species under conditions of ammonobasic synthesis (typically 573–673 K, 100–400 MPa) appears most likely.…”

Section: Introductionmentioning

confidence: 99%

Ammonothermal Synthesis and Characterization of Cs₂[Zn(NH₂)₄]

Richter

Alt

Schlücker

et al. 2016

Zeitschrift anorg allge chemie

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“…The solubility data for pure ammonium halides in liquid ammonia were reported at 298 K by Hunt (3,4), and at several temperatures by Kendall and Davidson (5). Solubilities In a wider temperature range, however, have not yet been reported.…”

Section: Introductionmentioning

confidence: 99%

Solubilities of ammonium iodide, ammonium bromide, and ammonium iodide-ammonium bromide mixture in liquid ammonia

Yamamoto¹,

Tokunaga²,

Sanga³

1986

J. Chem. Eng. Data

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Solubilities of ammonium Iodide and ammonium bromide In liquid ammonia were determined In the temperature range 270.0-350.0 K. Solubilities of these solutes In liquid ammonia Increased with the temperature, and the values of weight percent solubility increased from 77.34 to 83.01 wt % for ammonium Iodide, and from 88.71 to 73.19 wt % for ammonium bromide. Solubilities of the mixtures of ammonium Iodide and ammonium bromide (four weight ratios of NH4I/NH4Br = 0.37, 0.80, 1.48, and 2.95) In liquid ammonia were also determined In the temperature range 270.0-350.0 K. The relation between temperature and weight percent solubility for ammonium Iodide In liquid ammonia was shown by a smooth curve, but a bend point appeared on the solubility curve for ammonium bromide or Its mixture with ammonium Iodide In liquid ammonia. With increasing weight ratios of ammonium Iodide to ammonium bromide, the bend point on the solubility curve gradually moved toward lower temperature.

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Liquid Ammonia as a Solvent. III. The Solubility of Inorganic Salts at 25°

Cited by 37 publications

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Liquid ammonia research in 1933—A review

Liquid ammonia research in 1933—A review

Ammonothermal Synthesis and Characterization of Cs₂[Zn(NH₂)₄]

Solubilities of ammonium iodide, ammonium bromide, and ammonium iodide-ammonium bromide mixture in liquid ammonia

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Liquid Ammonia as a Solvent. III. The Solubility of Inorganic Salts at 25°

Cited by 37 publications

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Liquid ammonia research in 1933—A review

Liquid ammonia research in 1933—A review

Ammonothermal Synthesis and Characterization of Cs2[Zn(NH2)4]

Solubilities of ammonium iodide, ammonium bromide, and ammonium iodide-ammonium bromide mixture in liquid ammonia

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Ammonothermal Synthesis and Characterization of Cs₂[Zn(NH₂)₄]