“…In the whole cycloaddition reaction, experimental and theoretical studies have shown that the activation and ring-opening of epoxides are the decisive step [7]. Catalysts for epoxide activation such as metal oxides [8], metal salts [9], metal complexes [10], metal-organic skeleton materials [11], rare earth complexes [12], supported organometallic complexes [13], COF [14], small molecules [15], porous carbon from biomass [16], plasma [17], and Rhodamine dyes [18] have been reported. Among them, metal ion modified catalysts account for a large proportion, and the metals involved are potassium, calcium, magnesium, aluminum, zinc, iron, copper, niobium, chromium, zirconium, cobalt, lanthanum, indium and so on.…”