Linear C32H66 hydrocarbon in the mixed state with C10H22, C12H26, C14H30, C16H34 and C18H38: Comparison of strength of phases and role of tunnel-like defects

Shashikanth, P. B.

doi:10.1007/bf02899320

J Chem Sci

2003

DOI: 10.1007/bf02899320

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Linear C32H66 hydrocarbon in the mixed state with C10H22, C12H26, C14H30, C16H34 and C18H38: Comparison of strength of phases and role of tunnel-like defects

P. B. Shashikanth¹

Abstract: Strengths of β m , β o and U p phases of linear dotriacontane hydrocarbon in mixed state with certain shorter chain length homologues (SMOLLENCs), estimated from powder XRD analysis, are compared. The results suggest strong evidence in favour of tunnel-like defects (TLIDs).

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Superlattice configurations in linear chain hydrocarbon binary mixtures — Case ofn-C28H58:n-CxH2x+2 (x = 10,12,14,16)

Shashikanth¹,

Neelima²

2005

J Chem Sci

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Powder XRD data of mixtures of title compounds are interpreted in terms of superlattices (SL). It is suggested that SL configurations (orthorhombic-orthorhombic, orthorhombic-monoclinic, monoclinic-monoclinic) are realizable, because of discrete orientational changes in the alignment of molecules of n-C 28 H 58 hydrocarbon, through an angle mθ, where m = 1, 2, 3 … and angle θ has an average value of 3.3°. Supporting literature evidence on the inclinations are discussed.

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Superlattice configurations in linear chain hydrocarbon binary mixtures — Case ofn-C28H58:n-CxH2x+2 (x = 10,12,14,16)

Shashikanth¹,

Neelima²

2005

J Chem Sci

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Powder XRD studies onn-C28H58 :n-Cx H 2x+2 (x = 10, 12, 14, 16, 18) hydrocarbon mixtures: Phase strength analysis

Shashikanth

Neelima²

2006

Bull Mater Sci

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Linear C32H66 hydrocarbon in the mixed state with C10H22, C12H26, C14H30, C16H34 and C18H38: Comparison of strength of phases and role of tunnel-like defects

Abstract: Strengths of β m , β o and U p phases of linear dotriacontane hydrocarbon in mixed state with certain shorter chain length homologues (SMOLLENCs), estimated from powder XRD analysis, are compared. The results suggest strong evidence in favour of tunnel-like defects (TLIDs).

Cited by 2 publications

References 5 publications

Superlattice configurations in linear chain hydrocarbon binary mixtures — Case ofn-C28H58:n-CxH2x+2 (x = 10,12,14,16)

Superlattice configurations in linear chain hydrocarbon binary mixtures — Case ofn-C28H58:n-CxH2x+2 (x = 10,12,14,16)

Powder XRD studies onn-C28H58 :n-Cx H 2x+2 (x = 10, 12, 14, 16, 18) hydrocarbon mixtures: Phase strength analysis

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