volume 37, issue 14, P2245-2262 2018
DOI: 10.1021/acs.organomet.8b00229
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Abstract: The synthesis and characterization of a set of redox-active iron and ruthenium alkynyl complexes of general formula [[M]Cl (1-p) {C≡CC 6 H 5-m (C≡CFlu) m } (1+p) ][PF 6 ] n are reported (n = 0-1; m = 1-2; [M] = [Fe(η 5-C 5 Me 5)(κ 2-dppe)] and p = 1 or [M] = [trans-Ru(κ 2-dppe) 2 ] and p = 0-1). The linear and third-order nonlinear optical properties of these new organometallic complexes featuring phenylalkynyl ligands functionalized by 2-fluorenyl (Flu) groups were studied in their stable redox states. Their …

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