Linear and branched polyester resins based on dimethyl-2,5-furandicarboxylate for coating applications

Gubbels, Erik; Jasińska-Walc, Lidia; Noordover, Bart A. J.; Koning, Cor E.

doi:10.1016/j.eurpolymj.2013.06.019

Cited by 62 publications

(40 citation statements)

References 43 publications

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“…for all 45 catalysts) for poly(butylene 2,5furandicarboxylate) the same results are logically expected for PEF. Indeed, in a posterior work, published in 2013, by Noordover et al, 112 they mentioned similar coloration issues for other FDCA based polymers and suggested that they arise from sugar impurities present in FDCA, side reactions (e.g. decarboxylation) or even due to additives such as the catalyst.…”

Section: Poly(ethylene 25-furandicarboxylate)mentioning

confidence: 93%

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

et al. 2015

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Motivated by a general concern on sustainability and environmental issues, a sparkling search for renewable-based polymers has grown exponentially in recent years. This search definitely spotlighted polyesters derived from 2,5-furandicarboxylic acid, among other polymers, as some of the most promising, especially due to the resemblance of this renewable monomer to the well-known petroleum-based terephthalic acid, as well as for the possibility of preparing innovative materials. The huge number of recent papers and patents about this family of polymers explore aspects such diverse as synthesis with other renewable-based monomers, leading to the preparation of materials with enhanced thermo-mechanical, biodegradability and liquid crystalline properties, among other features. Additional aspects pursued in such studies are innovation in the synthetic approaches or its optimisation; and also the development of applications for everyday-life objects like for example packaging materials, especially bottles, textiles, coating, toners, among many other uses. Despite this intense activity little has been reviewed recently about this unique family of polyesters, or derived polymers, as the only reviews on the subject date-back from the last century. In this perspective, the present appraisal aims at contributing to fulfil this literature gap, covering recent aspects related with challenges of developing polyesters, polyamides, or other polymers from 2,5-furandicarboxylic acid and their precursors. Emphasis is placed on monomer synthesis, polymerisation reactions, catalysts and applications.A tribute to 2,5-furandicarboxylic acid excellency and the myriad of novel polyesters, but also polyamides, among other polycondensates, is comprehensively done.

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Section: Poly(ethylene 25-furandicarboxylate)mentioning

confidence: 93%

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

et al. 2015

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“…39 This improvement can obviously be correlated to the presence of bicyclic IIDMC units in the polymer chain for entry E with respect to entry a, demonstrating the effect of induced rigidity on the final material properties. In general an increased hardness is correlated with a higher Tg value, as can be observed in Table 4.…”

Section: Thermal Properties Of Sugar-based Polyestersmentioning

confidence: 93%

Isohexide and Sorbitol-Derived, Enzymatically Synthesized Renewable Polyesters with Enhanced T_g

et al. 2016

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Sugar-based polyesters derived from sorbitol and isohexides were obtained via solvent-free enzymatic catalysis. Pendant hydroxyl groups, coming from the sorbitol units, were present along the polyester backbone, whereas the two isohexides, namely, isomannide and isoidide dimethyl ester monomers, were selected to introduce rigidity into the polyester chains. The feasibility of incorporating isomannide as a diol compared to the isoidide dimethyl ester as acyl-donor via lipase-catalyzed polycondensation was investigated. The presence of bicyclic units resulted in enhanced T g with respect to the parent sorbitol-containing polyester lacking isohexides. The different capability of the two isohexides to boost the thermal properties confirmed the more flexible character provided by the isoidide diester derivative. Solvent-borne coatings were prepared by cross-linking the sugar-based polyester polyols with polyisocyanates. The increased rigidity of the obtained sugar-based polyester polyols led to an enhancement in hardness of the resulting coatings.

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“…36 The use of the furandiol BHMF has been the object of the preparation of aliphatic polyesters through enzymatic catalysis. 37 Some research has recently been published dealing with furan polyesteramides.…”

Section: Polycondensation Systemsmentioning

confidence: 99%

Progress of Polymers from Renewable Resources: Furans, Vegetable Oils, and Polysaccharides

et al. 2015

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Linear and branched polyester resins based on dimethyl-2,5-furandicarboxylate for coating applications

Cited by 62 publications

References 43 publications

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

Isohexide and Sorbitol-Derived, Enzymatically Synthesized Renewable Polyesters with Enhanced T_g

Progress of Polymers from Renewable Resources: Furans, Vegetable Oils, and Polysaccharides

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Linear and branched polyester resins based on dimethyl-2,5-furandicarboxylate for coating applications

Cited by 62 publications

References 43 publications

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

Isohexide and Sorbitol-Derived, Enzymatically Synthesized Renewable Polyesters with Enhanced Tg

Progress of Polymers from Renewable Resources: Furans, Vegetable Oils, and Polysaccharides

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Product

Resources

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Isohexide and Sorbitol-Derived, Enzymatically Synthesized Renewable Polyesters with Enhanced T_g