“…5) are overestimated by nearly a factor of two compared to the empirical intensity values of Ref. [24] validated by our present measurements. We have no explanation for this disagreement.…”
Section: Discussionsupporting
confidence: 76%
“…The detectivity threshold of the recordings corresponds to an intensity threshold of about 10 -29 cm/molecule which is at the state-of-the-art for the spectral region near 3.3 µm. Recent high sensitivity FTS spectrum with an absorption pathlength of 1058 m [24] reported only "M1" lines in the same region.…”
Section: Discussionmentioning
confidence: 98%
“…[14] for the E2 band and (ii) empirical intensities of M1 transitions calculated using a refined value of the effective dipole moment (EDM) parameter derived in Ref. [24]. The new fit of the M1 EDM parameter should use as input data the P, Q and R line intensities measured by FTS [24] and OFCEAS with P and R line intensities decreased by the corresponding E2 ab initio values (about 20 %) as experimental P and R line intensities involve both M1 and E2 contributions.…”
“…5) are overestimated by nearly a factor of two compared to the empirical intensity values of Ref. [24] validated by our present measurements. We have no explanation for this disagreement.…”
Section: Discussionsupporting
confidence: 76%
“…The detectivity threshold of the recordings corresponds to an intensity threshold of about 10 -29 cm/molecule which is at the state-of-the-art for the spectral region near 3.3 µm. Recent high sensitivity FTS spectrum with an absorption pathlength of 1058 m [24] reported only "M1" lines in the same region.…”
Section: Discussionmentioning
confidence: 98%
“…[14] for the E2 band and (ii) empirical intensities of M1 transitions calculated using a refined value of the effective dipole moment (EDM) parameter derived in Ref. [24]. The new fit of the M1 EDM parameter should use as input data the P, Q and R line intensities measured by FTS [24] and OFCEAS with P and R line intensities decreased by the corresponding E2 ab initio values (about 20 %) as experimental P and R line intensities involve both M1 and E2 contributions.…”
“…16. The 01111-00001 magnetic dipole band of the main CO2 isotopologue [56,58]. The band center of this band is 3004.012 cm -1 .…”
Section: Addition Of Magnetic Dipole Band Of 12 C 16 O2 At 33 µMmentioning
confidence: 91%
“…The detailed studies of this band providing the selection rules for the vibration-rotation transitions are presented in Refs [53,55]. The vibrational transition magnetic dipole moment of the 01111-00001 band was fitted to the line intensities measured with a Bruker IFS 125 HR FTS and a 30 m base multipass gas cell of the V.E.Zuev Institute of Atmospheric Optics SB RAS [56]. The line positions and intensities of this band were computed using the vibrational transition magnetic dipole moment and the set of the effective Hamiltonian parameters reported by Majcherova et al [57].…”
Section: Addition Of Magnetic Dipole Band Of 12 C 16 O2 At 33 µMmentioning
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