Limits of single crystal diamond surface mechanical polishing

Doronin, M.; Polyakov, S. N.; Кравчук, К. С.; Molchanov, S. P.; Lomov, A. A.; Troschiev, S. Yu.; Terentiev, Sergey

doi:10.1016/j.diamond.2018.05.016

Cited by 33 publications

(21 citation statements)

References 22 publications

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“…Laser polishing is performed by irradiating a laser beam with a certain energy density and wavelength on a material to melt or evaporate the surface layer of the material to obtain a smooth surface. This method does not require any mechanical abrasives or polishing tools and can polish surfaces with very complex topography that are difficult or impossible to polish with conventional polishing methods . Laser polishing has so far been used to polish a variety of materials, including diamonds, glass, ceramics, and various metals .…”

Section: Introductionmentioning

confidence: 99%

Laser polishing of Cu/PLA composite parts fabricated by fused deposition modeling: Analysis of surface finish and mechanical properties

et al. 2019

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Fused deposition modeling (FDM) technology decreases production time and cost in engineering industry, but with typical low surface quality. In this study, laser polishing was employed to improve surface quality of copper fiber/polylactide acid (Cu/PLA) composite parts fabricated by FDM. Surface roughness, surface morphology, dynamic mechanical analysis (DMA), and tensile properties were studied. The results showed that after laser polishing, the surface roughness was reduced by more than 91% (from 10.52 to 0.87 μm Sa) at the optimized parameters (the laser power of 5 W and the laser beam diameter of 200 μm). Laser polishing can effectively remove surface defects formed during FDM. DMA showed that the storage modulus, loss modulus, and glass transition temperature of Cu/PLA composites were significantly improved, because the Cu fibers and PLA matrix formed a strong interfacial adhesion after treatment. Moreover, the tensile strength and Young's modulus of the Cu/PLA composites sample also improved by laser polishing. The fracture morphologies were observed, and the possible strengthening mechanism was also discussed.

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Section: Introductionmentioning

confidence: 99%

Laser polishing of Cu/PLA composite parts fabricated by fused deposition modeling: Analysis of surface finish and mechanical properties

et al. 2019

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“…When an SCD (100) is polished by a mechanical method, such as scaife, the polishing rate in the <100> direction is much higher than that in the <110> direction. Thus, streak-like structures are easily formed on the surface 10,11 . On the other hand, because the surface texture depending on the crystal direction is not observed on the SCD (100) surface polished by PAP, it is presumed that not only mechanical action exists in the PAP of SCD 8 .…”

Section: Resultsmentioning

confidence: 99%

Damage-free highly efficient plasma-assisted polishing of a 20-mm square large mosaic single crystal diamond substrate

Liu

Sugawara

Yoshitaka

et al. 2020

Sci Rep

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Plasma-assisted polishing (PAP) as a damage-free and highly efficient polishing technique has been widely applied to difficult-to-machine wide-gap semiconductor materials such as 4H-SiC (0001) and GaN (0001). In this study, a 20-mm square large mosaic single crystal diamond (SCD) substrate synthesized by microwave plasma chemical vapor deposition (CVD) was polished by PAP. Argon-based plasma containing oxygen was used in PAP to modify the surface of quartz glass polishing plate, and a high material removal rate (MRR) of 13.3 μm/h was obtained. The flatness of SCD polished by PAP measured by an interferometer was 0.5 μm. The surface roughness measured by both scanning white light interferometer (SWLI) (84-μm square) and atomic force microscope (AFM) (5-μm square) was less than 0.5 nm Sq. The micro-Raman spectroscopy measurement results of mosaic SCD substrate processed by PAP showed that residual stress and non-diamond components on the surface after PAP processing were below the detection limit.

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“…The BDD single crystals with boron concentration of 0.13 at.% in the bulk were cut by a technological laser into plates with as-grown {111} faces for detailed studies. The surfaces opposite to the as-grown one were polished to remove the graphitized layer remaining after cutting [ 20 ].…”

Section: Methodsmentioning

confidence: 99%

Structure Investigations of Islands with Atomic-Scale Boron–Carbon Bilayers in Heavily Boron-Doped Diamond Single Crystal: Origin of Stepwise Tensile Stress

Polyakov

Денисов

et al. 2021

Nanoscale Res Lett

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The detailed studies of the surface structure of synthetic boron-doped diamond single crystals using both conventional X-ray and synchrotron nano- and microbeam diffraction, as well as atomic force microscopy and micro-Raman spectroscopy, were carried out to clarify the recently discovered features in them. The arbitrary shaped islands towering above the (111) diamond surface are formed at the final stage of the crystal growth. Their lateral dimensions are from several to tens of microns and their height is from 0.5 to 3 μm. The highly nonequilibrium conditions of crystal growth enhance the boron solubility and, therefore, lead to an increase of the boron concentrations in the islands on the surface up to 1022 cm−3, eventually generating significant stresses in them. The stress in the islands is found to be the volumetric tensile stress. This conclusion is based on the stepwise shift of the diamond Raman peak toward lower frequencies from 1328 to 1300 cm−1 in various islands and on the observation of the shift of three low-intensity reflections at 2-theta Bragg angles of 41.468°, 41.940° and 42.413° in the X-ray diffractogram to the left relative to the (111) diamond reflection at 2theta = 43.93°. We believe that the origin of the stepwise tensile stress is a discrete change in the distances between boron–carbon layers with the step of 6.18 Å. This supposition explains also the stepwise (step of 5 cm−1) behavior of the diamond Raman peak shift. Two approaches based on the combined application of Raman scattering and X-ray diffraction data allowed determination of the values of stresses both in lateral and normal directions. The maximum tensile stress in the direction normal to the surface reaches 63.6 GPa, close to the fracture limit of diamond, equal to 90 GPa along the [111] crystallographic direction. The presented experimental results unambiguously confirm our previously proposed structural model of the boron-doped diamond containing two-dimensional boron–carbon nanosheets and bilayers.

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Limits of single crystal diamond surface mechanical polishing

Cited by 33 publications

References 22 publications

Laser polishing of Cu/PLA composite parts fabricated by fused deposition modeling: Analysis of surface finish and mechanical properties

Laser polishing of Cu/PLA composite parts fabricated by fused deposition modeling: Analysis of surface finish and mechanical properties

Damage-free highly efficient plasma-assisted polishing of a 20-mm square large mosaic single crystal diamond substrate

Structure Investigations of Islands with Atomic-Scale Boron–Carbon Bilayers in Heavily Boron-Doped Diamond Single Crystal: Origin of Stepwise Tensile Stress

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