2018
DOI: 10.1021/acsami.8b13031
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Lignin-Containing Photoactive Resins for 3D Printing by Stereolithography

Abstract: Generating compatible and competitive materials that are environmentally sustainable and economically viable is paramount for the success of additive manufacturing using renewable materials. We report the successful application of renewable, modified lignin-containing photopolymer resins in a commercial stereolithography system. Resins were fabricated within operable ranges for viscosity and cure properties, using up to 15% modified lignin by weight with the potential for higher amounts. A four-fold increase i… Show more

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Cited by 152 publications
(146 citation statements)
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“…17 Resins with high viscosity do not adequately self-level and recoat the surface of the resin tray between layers, resulting in long print times or unsuccessful prints. [18][19][20] An alternative design strategy is to employ cyclic, branched, or dendritic polymer architectures, or cross-linked unimolecular particles, that have a lower intrinsic viscosity relative to a linear polymer of comparable molecular weight. 21,22 In this report, we demonstrate a protein-based resin for vat photopolymerization using bovine serum albumin (BSA) that can be utilized to 3D print objects with complex geometries.…”
Section: Introductionmentioning
confidence: 99%
“…17 Resins with high viscosity do not adequately self-level and recoat the surface of the resin tray between layers, resulting in long print times or unsuccessful prints. [18][19][20] An alternative design strategy is to employ cyclic, branched, or dendritic polymer architectures, or cross-linked unimolecular particles, that have a lower intrinsic viscosity relative to a linear polymer of comparable molecular weight. 21,22 In this report, we demonstrate a protein-based resin for vat photopolymerization using bovine serum albumin (BSA) that can be utilized to 3D print objects with complex geometries.…”
Section: Introductionmentioning
confidence: 99%
“…Truly arbitrary 3D architectures with high resolution and good surface finish can be achieved by SLA, but the printing materials are restricted to photopolymer‐based materials . Additionally, the efficiency of SLA is relatively low . The widest possible range of materials can be printed by SLA in high resolution.…”
Section: D Printing Technologymentioning
confidence: 99%
“…Over the last years, some natural products have been (meth)acrylated or acrylated to become printable by means of SLA or DLP and most of them are specifically conceived for the preparation of hydrogels. [14][15][16][17][18][19][20][21][22][23][24][25] Among bio-derived molecules, cyclodextrins (CDs) are interesting candidates. Cyclodextrins are macrocyclic oligosaccharides obtained via the degradation of starch catalyzed by the glycosyl transferase enzyme.…”
Section: Doi: 101002/mame202000350mentioning
confidence: 99%