Lightweight, Flexible, and Thermal Insulating Carbon/SiO2@CNTs Composite Aerogel for High‐Efficiency Microwave Absorption
Xiaohan Wang,
Ye Yuan,
Xianxian Sun
et al.
Abstract:A complex electromagnetic environment is a formidable challenge in national defense areas. Microwave‐absorbing materials are considered as a strategy to tackle this challenge. In this work, lightweight, flexible, and thermal insulating Carbon/SiO2@CNTs (CSC) aerogel is successfully prepared coupled with outstanding microwave absorbing performance, through freeze‐drying and high‐temperature annealing techniques. The CSC aerogel shows a strong reflection loss (−55.16 dB) as well as wide effective absorbing bandw… Show more
“…S6 and Fig. S6 ), when the thickness reaches one-fourth of the wavelength of the incident wave, an interference cancellation occurs between the incident wave and the reflected wave, and in this case the thickness is the optimal thickness corresponding to the matching frequency [ 43 , 75 ]. Figure S5 shows that the measured matching thickness is basically consistent with the simulated thickness of the half-wavelength loss.…”
Two-dimensional carbon-based materials have shown promising electromagnetic wave absorption capabilities in mid- and high-frequency ranges, but face challenges in low-frequency absorption due to limited control over polarization response mechanisms and ambiguous resonance behavior. In this study, we propose a novel approach to enhance absorption efficiency in aligned three-dimensional (3D) MXene/CNF (cellulose nanofibers) cavities by modifying polarization properties and manipulating resonance response in the 3D MXene architecture. This controlled polarization mechanism results in a significant shift of the main absorption region from the X-band to the S-band, leading to a remarkable reflection loss value of − 47.9 dB in the low-frequency range. Furthermore, our findings revealed the importance of the oriented electromagnetic coupling in influencing electromagnetic response and microwave absorption properties. The present study inspired us to develop a generic strategy for low-frequency tuned absorption in the absence of magnetic element participation, while orientation-induced polarization and the derived magnetic resonance coupling are the key controlling factors of the method.
“…S6 and Fig. S6 ), when the thickness reaches one-fourth of the wavelength of the incident wave, an interference cancellation occurs between the incident wave and the reflected wave, and in this case the thickness is the optimal thickness corresponding to the matching frequency [ 43 , 75 ]. Figure S5 shows that the measured matching thickness is basically consistent with the simulated thickness of the half-wavelength loss.…”
Two-dimensional carbon-based materials have shown promising electromagnetic wave absorption capabilities in mid- and high-frequency ranges, but face challenges in low-frequency absorption due to limited control over polarization response mechanisms and ambiguous resonance behavior. In this study, we propose a novel approach to enhance absorption efficiency in aligned three-dimensional (3D) MXene/CNF (cellulose nanofibers) cavities by modifying polarization properties and manipulating resonance response in the 3D MXene architecture. This controlled polarization mechanism results in a significant shift of the main absorption region from the X-band to the S-band, leading to a remarkable reflection loss value of − 47.9 dB in the low-frequency range. Furthermore, our findings revealed the importance of the oriented electromagnetic coupling in influencing electromagnetic response and microwave absorption properties. The present study inspired us to develop a generic strategy for low-frequency tuned absorption in the absence of magnetic element participation, while orientation-induced polarization and the derived magnetic resonance coupling are the key controlling factors of the method.
“…RL ≤ −10 dB was defined as effective absorption. According to transmission line theory and the electromagnetic parameters measured in the 2-18 GHz range, the corresponding RL was calculated according to the following equations [39]: In general, reflection loss (RL) is used to evaluate the MA performance of a material. RL ≤ −10 dB was defined as effective absorption.…”
Section: Ma Performancementioning
confidence: 99%
“…RL ≤ −10 dB was defined as effective absorption. According to transmission line theory and the electromagnetic parameters measured in the 2-18 GHz range, the corresponding RL was calculated according to the following equations [39]:…”
A nanoparticle-anchored three-dimensional microsphere flower-structured layered double hydroxide (LDH) material with Fe3O4 particles was successfully prepared using simple hydrothermal and hot solvent methods. Micro-nanostructured Fe3O4@LDHs (SLF) composites balance microwave absorption, corrosion protection, and UV aging resistance. The minimum reflection loss value of SLF is −35.75 dB at 14.16 GHz, when the absorber thickness is 8 mm, and the absorption bandwidth at this frequency is up to 2.56 GHz for RL values less than −10 dB, while the LL is only 1 GHz. The SLF /EP coating has not only excellent microwave absorption performance but also excellent corrosion and UV aging resistance performance. The coating still has some anti-corrosion effect after 10 d of immersion. This work is intended as a reference for the development of new coatings with excellent microwave absorption properties as well as corrosion and UV aging resistance for wind turbine tower barrels (seaside wind power generation equipment) surfaces.
“…Electromagnetic (EM) waves serve as crucial carriers of energy in various communication technologies; however, the widespread proliferation of electronic devices and wireless communication technologies has inevitably led to EM wave pollution, which causes interference risks to precision instruments and potential threat to human health. , To tackle these problems, researchers have developed various EM wave absorption materials, including traditional magnetic materials, dielectric materials, − metal–organic frameworks (MOFs), − and carbon-based materials such as carbon nanotubes (CNTs) and carbon fiber (CF). − Recently, with the trend toward miniaturization and lightweight design in electronic and communication devices, the demand for EM wave absorbers that are ultralight, ultrathin, highly efficient, and capable of broad bandwidth absorption has intensified. This development trend renders conventional magnetic or dielectric powder and single-component carbon-based materials inadequate for practical application.…”
Aerogel-based composites, renowned for their three-dimensional (3D) network architecture, are gaining increasing attention as lightweight electromagnetic (EM) wave absorbers. However, attaining high reflection loss, broad effective absorption bandwidth (EAB), and ultrathin thickness concurrently presents a formidable challenge, owing to the stringent demands for precise structural regulation and incorporation of magnetic/dielectric multicomponents with synergistic loss mechanisms within the 3D networks. In this study, we successfully synthesized a 3D hierarchical porous Fe 3 O 4 /MoS 2 /rGO/Ti 3 C 2 T x MXene (FMGM) composite aerogel via directional freezing and subsequent heat treatment processes. Owing to their ingenious structure and multicomponent design, the FMGM aerogels, featured with abundant heterogeneous interface structure and magnetic/dielectric synergism, show exceptional impedance matching characteristics and diverse EM wave absorption mechanisms. After optimization, the prepared ultralight (6.4 mg cm −3 ) FMGM-2 aerogel exhibits outstanding EM wave absorption performance, achieving a minimal reflection loss of −66.92 dB at a thickness of 3.61 mm and an EAB of 6.08 GHz corresponding to the thickness of 2.3 mm, outperforming most of the previously reported aerogel-based absorbing materials. This research presents an effective strategy for fabricating lightweight, ultrathin, highly efficient, and broad band EM wave absorption materials.
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