Al-Mn-Zn ternary system is experimentally investigated at 400 ∘ C using diffusion couples and key alloys. Phase relationships and homogeneity ranges are determined for binary and ternary compounds using EPMA, SEM/EDS, and XRD. Reported ternary compound T3 (Al 11 Mn 3 Zn 2 ) is confirmed in this study and is denoted as 2 in this paper. Two new ternary compounds ( 1 and 3 ) are observed in this system at 400 ∘ C. 1 is determined as a stoichiometric compound with the composition of Al 31 Mn 8 Zn 11 . 3 has been found to have homogeneity range of Al Mn Zn ( = 9-13 at%; = 11-15 at%; = 75-77 at%). The binary compounds Al 4 Mn and Al 11 Mn 4 exhibit limited solid solubility of around 6 at% and 4 at% Zn, respectively. Terminal solid solution Al 8 Mn 5 is found to have maximum ternary solubility of about 10 at% Zn. In addition, ternary solubility of Al-rich -Mn at 400 ∘ C is determined as 4 at% Zn. Zn-rich -Mn has a ternary solubility of 3 at% Al. The solubility of Al in Mn 5 Zn 21 is measured as 5 at%. Based on the current experimental results, the isothermal section of Al-Mn-Zn ternary system at 400 ∘ C has been constructed.