Covalent organic framework (COF) materials are characterized
by
periodic π arrays and orderly open channels, but poor electrical
conductivity limits their applications in opt-electric fields. In
this paper, 2,4,6-tris(4-formylphenyl)-1,3,5-triazine (TFPT) and 2,4,6-tris(4-aminophenyl)-1,3,5-triazine
(TAPT) were used to synthesize TPT-COF with a redox unit of triazine
by Schiff base reaction. In order to improve the electrical conductivity
of TPT-COF, we prepared Nickel Nanowires (NiNWs) by a chemical reduction
method and then prepared TPT-COF/NiNWs composites with different loading
amounts of NiNWs. With the addition of NiNWs, the two materials are
assembled to obtain a nanorod structure by using the π–π
packing effect of the COF and the bridging of function conductive
NiNWs. The electrochemical properties of composite electrode materials
with different contents of NiNWs were tested, and TPT-COF/NiNWs-15%
exhibited better electrochemical performance in sulfuric acid electrolytes.
The specific capacitance of TPT-COF/NiNWs-15% is 343 F/g, and the
high power density is 10945 W/kg. The addition of NiNWs provides a
good strategy to improve the electrical performance of the COF-based
electrode materials.