A series of recent experimental and theoretical papers 1 " 8 have investigated the properties of thermally excited bulk and surface magnons observed by Brillouin scattering from ferromagnetic metals, both polycrystalline and amorphous. Most of this work has been performed on samples which are considerably thicker than the penetration depth of the incident light and hence also than the wavelength of the observed magnons. Here we report on Brillouin scattering from thin films (<200 nm), in which we have observed for the first time a substructure in the bulk magnon scattering. We perform our experiments on amorphous sputtered films of Fe 80 B 20 .It is well known that a bulk magnon of wave vector q propagating perpendicular to an applied magnetic field H has a frequency v given by 9 ' 10where y is the gyromagnetic ratio, M the magnetization of the sample, and D the spin-wave stiffness. In a thin film with either complete pinning or no pinning at the surface, the wavevector component q x perpendicular to the film is quantized according to q x = n7i/L, where L is the sample thickness and n is an integer. For the case of no pinning, n = 0, 1,...; when pinning is present, n-1, 2,.... Clearly, the smaller the thickness, the larger the separation between the (1948). 8 C. Popescu and H. K. Henisch, Phys. Rev. B 14, 517 (1976).different modes. In thicker samples which have been studied earlier by light scattering, 1 " 3 ' 8 the separations were smaller than experimental resolution, and only a single broad and asymmetric s.peak was observed. sThe fact that our samples are metals rather than insulators has a negligible effect on the mode positions of Eq. (1), for given the resistivity of our amorphous materials of roughly 200 PL12 cm, the skin depth is over ten times the thickness of even our thickest film throughout the investigated frequency range. However, we expect the large absorption coefficient of the metal to affect the light-scattering selection rules. In conventional scattering studies of transparent materials, there is a selection rule based on wave-vector conservation between incident v and scattered light and the excitation itself. However, as recently shown, 2 ' 4 ' 8 the large absorption coefficient effectively leads to a spreading inside the metal, of the light's wave-vector component perpendicular to the surface. Therefore, for a given scattering geometry one can simultaneously scatter from a series of spin waves with different values of q x . The Brillouin spectra were taken with a fivepass Fabry-Perot interferometer. Thin samples of varying thicknesses of amorphous Fe 80 B 20 , deposited by sputtering on silicon substrates, 8 * 11 ' 12 We report the first observation of standing spin-wave modes by means of Brillouin light scattering in thin sputtered films of amorphous metallic Fe 80 B 2 o. Results agree with a classical theory and permit determination of spin-wave stiffness D~(1.4±0.2) xio* 9 Oe cm 2 . The value of D is twice as large as that obtained from low-temperature magnetization measurements.