Ligand substitution reaction in the parent cluster (μ3-FcCHC)FeCo2(CO)9 and structural characterization of its CO substituted derivatives

Han, Limin; Suo, Quan‐Ling; Wang, Yibing; Ye, Jiehui; Zhu, Na; Leng, Xuebing; Sun, Jing

doi:10.1016/j.poly.2005.01.018

Cited by 12 publications

(2 citation statements)

References 16 publications

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“…Octacarbonyl dicobalt and trimethylsilylacetylene were obtained from Alfa-Aesar Chem. Ferrocenylacetylene, diferrocenylacetylene, Co 2 (CO) 6 (μ 2 -trimethylsilyl acetylene), and Co 2 (CO) 6 (μ 2 -diferrocenylacetylene) were prepared according to previously reported methods [23,24]. Dioxane was distilled under nitrogen over sodium metal.…”

Section: General Materials and Instrumentsmentioning

confidence: 99%

Synthesis of tetraferrocenylbenzene by cycloaddition reaction with alkyl cobalt clusters as reaction precursors

Xie

Han

Zhu

et al. 2015

Journal of Coordination Chemistry

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2015) Synthesis of tetraferrocenylbenzene by cycloaddition reaction with alkyl cobalt clusters as reaction precursors, Journal of Coordination Chemistry, 68:3, 449-460, Two tetraferrocenylbenzene derivatives, 1-trimethylsilyl-2,3,4,5-tetraferrocenylbenzene (1) and 1,2,4,5-tetraferrocenylbenzene (2), were synthesized by cycloaddition reactions of alkynes with Co 2 (CO) 6 (μ 2 -alkyne) as reaction precursors and characterized by elemental analysis, FT-IR, NMR, and MS. The molecular structures of 1 and 2 were identified by single-crystal X-ray diffraction. The redox properties were studied by cyclic voltammetry and square wave voltammetry, which indicated stronger electronic communication among ferrocenyl units.

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Section: General Materials and Instrumentsmentioning

confidence: 99%

Synthesis of tetraferrocenylbenzene by cycloaddition reaction with alkyl cobalt clusters as reaction precursors

Xie

Han

Zhu

et al. 2015

Journal of Coordination Chemistry

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“…In this paper, we synthesized an alkynyl-bridged diferrocenyl azobenzene derivatives by using documental methods [7][8][9][10], and investigated the photoinduced azo isomerization and redox potential shift of ferrocene.…”

Section: Introductionmentioning

confidence: 99%