Ligand-Dominated Activation of CO2 and CS2 by the Putative Nickel Phosphiniminato Intermediates
Changguang Yao,
Théo P. Gonçalves,
Xiufang Wang
et al.
Abstract:Room-temperature photoactivation of the first-and second-generation PN 3 P-pincer nickel azido complexes 1a and 1b in the presence of CO 2 or CS 2 afforded N-bound carbamates, dithiocarbamates, and isothiocyanates, providing insights into CO 2 and CS 2 activation and demonstrating how a seemingly small difference in the ligand structure significantly influences the reactivity. Theoretical calculations disclosed that the charge of the phosphorus atom plays a critical role in determining the nitrogen atom transf… Show more
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