2020
DOI: 10.1002/aoc.5935
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Ligand directed synthesis of a unprecedented tetragonalbipyramidal copper (II) complex and its antibacterial activity and catalytic role in oxidative dimerisation of 2‐aminophenol

Abstract: In pursuit of the significant contribution of copper ion in different biological processes, this research work describes the synthesis, X-ray structure, Hirshfeld surface analysis, oxidative dimerization of 2-aminophenol and antibacterial activity of a newly designed copper (II)-Schiff base complex, [Cu(L) 2 ] (1), [Schiff base (HL) = 2-(2-methoxybenzylideneamino)phenol]. X-ray structural analysis of 1 reveals that the Cu (II) complex crystallizes in a cubic crystal system with Ia-3d space group. The Cu (II) c… Show more

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Cited by 28 publications
(13 citation statements)
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References 77 publications
(86 reference statements)
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“…In the design of functional coordination compounds, the role of the polydentate ligand, especially Schiff base as a tailormade chelating ligand is praiseworthy. 21,22 The fine tunability, straightforward synthetic procedure, and simple reaction setup make it a versatile and flexible chelating scaffold in coordination chemistry. 23 The transition metals in coupling with Schiff bases show interesting properties and applications in designing molecular magnets, electrical-transport materials, smart catalysts, efficient chemosensors, etc.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…In the design of functional coordination compounds, the role of the polydentate ligand, especially Schiff base as a tailormade chelating ligand is praiseworthy. 21,22 The fine tunability, straightforward synthetic procedure, and simple reaction setup make it a versatile and flexible chelating scaffold in coordination chemistry. 23 The transition metals in coupling with Schiff bases show interesting properties and applications in designing molecular magnets, electrical-transport materials, smart catalysts, efficient chemosensors, etc.…”
Section: Introductionmentioning
confidence: 99%
“…23 The transition metals in coupling with Schiff bases show interesting properties and applications in designing molecular magnets, electrical-transport materials, smart catalysts, efficient chemosensors, etc. 5,6,[24][25][26][27][28] Therefore, scientists are actively engrossed in the design and synthesis of metal complexes along with their functional activities. Copper and nickel metal ions are considered biologically important metal ions.…”
Section: Introductionmentioning
confidence: 99%
“…Therefore, structural and functional adaptation of the metallo-catalysts grabs tremendous attention in bioinspired catalysis. [6][7][8][9] Traditionally, the design of environmentally sustainable and earth-abundant metal catalysts holds a great promise for the effective transformations of small molecules to value-added products. [10][11][12][13][14][15][16][17][18][19][20][21] Among the different d-block metals, cobalt forms highly stable complexes with multidentate ligands under steric and electronic influences and shows great expediency in well-defined molecular forms.…”
Section: Introductionmentioning
confidence: 99%
“…Schiff bases are an important class of molecules for their easy preparative accessibility, structural versatility and diverse applications in modern sciences [1][2][3][4][5][6][7]. They exhibit interesting coordinative capability towards metal ions and the metal-Schiff base compounds/chelates have been considered as important compounds for the development of magnetic materials, highly efficient catalysts, bio-inspired oxidation processes, smart photoluminescent materials, therapeutic agents and so on [8][9][10][11][12]. Schiff bases containing different hetero atoms as donor centres like N, O, S, P have emerged as a promising field of research in coordination chemistry since the metal-Schiff base compounds may tune the morphological, physiological, and pharmacological properties to some great extent [13][14][15].…”
Section: Introductionmentioning
confidence: 99%