“…The allocation factor was based on the ratio between the flow rate of the CDP and the flow rate of each scenario of the WMP. This method of defining the flow rate has been discussed and implemented in various publications. ,− Another example of a similar approach is the consideration of module D within the EN 15804:2012 + A2:2019 for the inclusion of information beyond the cradle-to-gate scope in construction product LCAs. , These allocation factors are presented in Table for 11 different scenarios defined from the operating ranges presented in Wet milling processsection.…”
This article evaluates two processes, wet milling and chemical depolymerization, for the end-of-life of wood waste in terms of environmental performance (ex ante life cycle assessment), energy balance, and economic analysis of the operating costs. Cellulose, hemicellulose, and lignin are essential components with numerous applications. The study provides valuable insights for industry stakeholders, policymakers, and researchers of the wet milling process (WMP), which is scarcely reported in the literature. The chemical depolymerization process (CDP) is discontinuous and more energy-intensive, while the WMP is a continuous reaction demanding milder conditions and shorter times. However, the milling process requires a pretreatment to reduce the wood chip size. Economic analysis shows that the CDP has lower operational costs when considering the average European electricity price in 2019. This is a result of the price differences between steam and electricity. For lower electricity prices such as in France or using utility-scale solar photovoltaics, the WMP has lower operational costs. The WMP also outperforms the CDP in most environmental indicators, such as global warming potential, particularly when using green electricity technologies.
“…The allocation factor was based on the ratio between the flow rate of the CDP and the flow rate of each scenario of the WMP. This method of defining the flow rate has been discussed and implemented in various publications. ,− Another example of a similar approach is the consideration of module D within the EN 15804:2012 + A2:2019 for the inclusion of information beyond the cradle-to-gate scope in construction product LCAs. , These allocation factors are presented in Table for 11 different scenarios defined from the operating ranges presented in Wet milling processsection.…”
This article evaluates two processes, wet milling and chemical depolymerization, for the end-of-life of wood waste in terms of environmental performance (ex ante life cycle assessment), energy balance, and economic analysis of the operating costs. Cellulose, hemicellulose, and lignin are essential components with numerous applications. The study provides valuable insights for industry stakeholders, policymakers, and researchers of the wet milling process (WMP), which is scarcely reported in the literature. The chemical depolymerization process (CDP) is discontinuous and more energy-intensive, while the WMP is a continuous reaction demanding milder conditions and shorter times. However, the milling process requires a pretreatment to reduce the wood chip size. Economic analysis shows that the CDP has lower operational costs when considering the average European electricity price in 2019. This is a result of the price differences between steam and electricity. For lower electricity prices such as in France or using utility-scale solar photovoltaics, the WMP has lower operational costs. The WMP also outperforms the CDP in most environmental indicators, such as global warming potential, particularly when using green electricity technologies.
“…FT-IR and solid-state 31 P MAS NMR spectroscopic investigations of MCC and P-CNCs were performed to study the structure of P-CNCs. Significantly, the stretching vibration peak of -OH groups at 3400 cm −1 and the C-H symmetrical stretching vibration peak at 2903 cm −1 were observed in the FT-IR spectra of both MCC and P-CNCs (Fig.…”
Section: Structural and Morphological Properties Of P-cncsmentioning
confidence: 99%
“…Life cycle assessment (LCA) is an internationally standardized method to quantitatively analyse the cumulative environmental burdens of products, services and technologies, 29,30 and it significantly benefits the design and optimisation of novel production processes. 31 In the past few years, LCA has been widely used to evaluate the environmental performance of nanocellulose, e.g., CNCs and CNFs. 32 However, there has been no LCA study on P-CNC production, resulting in difficulties in process comparison, adaptation and optimisation.…”
Phosphorylated cellulose nanocrystals (P-CNCs) are important derivatives of cellulose nanocrystals (CNCs), which have attracted much attention in food, cosmetics and biomedicines. However, the lack of suitable industrial manufacturing technology impedes...
“…Life cycle assessment (LCA) is performed to design 27 and optimize 28 novel chemical processes and products, especially at an early stage, 29 in both laboratory and industrial‐scale, 30 by considering the environmental sustainability performance across all stages of a product's life cycle 31 . For example, an early stage LCA study of nanocellulose yarn revealed that wet‐spinning was cleaner than electrospinning, and the efforts on heat recovery and improving solvent exchange presents ecofriendly benefits, which will enable precise optimization in future 32 .…”
The commercialization of cellulose nanocrystals (CNCs) is currently limited by its environmental impact of high water consumption and brine wastewater generation. Here, a combined process integrating the production of CNCs and calcium sulfate whiskers (CSWs) was proposed to achieve complete utilization of the waste acid, and the corresponding environmental performance was evaluated by life cycle assessment (LCA). Accordingly, we prepared fibrous CSWs with an average length of 309 μm and an average aspect ratio of 57 under optimum conditions. The LCA results demonstrated the superior environmental performance of the combined process, especially for CNC production, and the impact values reduced by 45.6% on average. Moreover, the cost of producing 20 g of CNCs decreased from 3.04 CNY (traditional process) to 1.66 CNY (combined process). Therefore, this combined production process is eco‐efficient and economically scalable for the industrial production of CNCs.
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