LIF Study of the b1Σ+(b0+) ↔ X3Σ−(X10+,X21) Transitions of SbH and SbD

Infrared and near infrared emission spectra of SbH and SbD

“…1 shows the spectrum of the b 1 R + -X 2 1 transition of SbD that we obtained. Our line positions agree well with those reported by Shestakov et al [8] within their error limits.…”

“…Recently, Beutel et al [7] measured the 0-0 and 1-1 bands of the a 1 D-X 3 R À transitions of SbH and SbD with a Fourier transform spectrometer. Shestakov et al [8] studied the b 1 R + -X 3 R À transitions of SbH and SbD by pulsed laser excitation spectroscopy. The spectra of Shestakov et al [8] directly measured the large spin splitting of about 660 cm À1 between the X 1 0 + and X 2 1 spin components of the X 3 R À state.…”

“…Shestakov et al [8] studied the b 1 R + -X 3 R À transitions of SbH and SbD by pulsed laser excitation spectroscopy. The spectra of Shestakov et al [8] directly measured the large spin splitting of about 660 cm À1 between the X 1 0 + and X 2 1 spin components of the X 3 R À state. More recently, Wang et al [9] observed infrared spectra of several antimony hydrides including SbH and SbD in solid matrices.…”

LIF Studies of theÃ1A′ States of BiOH and BiOD

“…) obtained from an improved analysis of the X 3 AЈ 3 X 1 AЈ emission spectrum in the near-infrared (1,5). The fit of 12 bandheads showed a standard deviation of 0.44 cm Ϫ1 and thus confirmed the assignment of the ⌬K a ϭ 0 and Ϯ1 subbands to a single vibronic transition.…”

“…4 Deduced from analysis of the à 1 AЈ 4 X 3 AЈ band. 5 Deduced from analysis of the à 1 AЈ 4 X 1 AЈ band.…”