Librational motion in macromolecules and low-temperature δ-relaxation

Ryzhov, V. A.; Byershtein, V.A.

doi:10.1016/0032-3950(89)90222-0

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1997

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“…Ryzhov and Byershtein have demonstrated that broad infrared absorption bands of several glassy polymers are caused by torsional vibrations of molecular groups similar in size to the polymer repeat units. 38 Their explanation of these bands stresses the importance of intermolecular potentials in determining the characteristics of the observed librational motion. This may provide an alternative approach for understanding the librational motions observed in our experiments.…”

Section: Discussionmentioning

confidence: 97%